copper;silver | 98002-69-8

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: copper;silver
• CAS: 98002-69-8
• 化学式: Ag₂Cu
• 分子量: 279.282
• InChiKey: YCKOAAUKSGOOJH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  copper;silver 、 奥苷菊环 生成 silver(azulene)(1+)
  参考文献：
  名称：

  Ionization potentials and reactivity of coinage metal clusters

  摘要：

  The ionization potentials of several homoatomic and heteroatomic coinage metal clusters have been determined utilizing charge-transfer bracketing and Fourier transform ion cyclotron resonance (FTICR) mass spectrometry. The clusters studied were Ag(n), Au(n), Cu(m), and Ag(k)Cu(l), where n = 2,3,5, m = 2,3, and k and l = 1,2. Atomic ionization potentials were also verified for each of the above metals as a test of the bracketing method. This work represents one of the first measurements of adiabatic ionization potentials for any of the above clusters. A number of additional reactions were observed between several of the charge-transfer agents and metal cluster ions, including some which resulted in metal-metal bond cleavage.

  DOI：

  10.1021/j100182a013

文献信息

• Ionization potentials and reactivity of coinage metal clusters
  作者：M. A. Cheeseman、J. R. Eyler

  DOI：10.1021/j100182a013

  日期：1992.2

  The ionization potentials of several homoatomic and heteroatomic coinage metal clusters have been determined utilizing charge-transfer bracketing and Fourier transform ion cyclotron resonance (FTICR) mass spectrometry. The clusters studied were Ag(n), Au(n), Cu(m), and Ag(k)Cu(l), where n = 2,3,5, m = 2,3, and k and l = 1,2. Atomic ionization potentials were also verified for each of the above metals as a test of the bracketing method. This work represents one of the first measurements of adiabatic ionization potentials for any of the above clusters. A number of additional reactions were observed between several of the charge-transfer agents and metal cluster ions, including some which resulted in metal-metal bond cleavage.