Sodium tetrabromoaurate(III) hydrate | 10378-49-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Sodium tetrabromoaurate(III) hydrate
• 英文别名: sodium;tetrabromogold(1-);hydrate
• CAS: 10378-49-1
• 化学式: AuBr₄*2H₂O*Na
• 分子量: 575.603
• InChiKey: DCARRTFPXWVHEC-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -0.44
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• TSCA：
  Yes
• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 安全说明：
  S26,S36

反应信息

• 作为反应物：
  描述：

  [Pd(diethylenetriamine)Cl]Cl 、 Sodium tetrabromoaurate(III) hydrate 在 盐酸 作用下， 以 水 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Synthesis and structure of double complex salts [Pd(Dien)Cl][AuX4] (X = Cl, Br), [Pd(Dien)Br][AuBr4], and initial complex [Pd(Dien)Cl]Cl

  摘要：

  New double complex salts were prepared: [Pd(Dien)Cl][AuCl4] (I), [Pd(Dien)Cl][AuBr4] (II), and [Pd(Dien)Br][AuBr4] (III). The compounds were studied by elemental analysis, IR spectroscopy, X-ray powder diffraction, and X-ray crystallography. Crystallographic data for I: a = 16.6661(5) angstrom, b = 12 7175(4) angstrom, c = 12.8936(4) angstrom, beta = 97.621(1)degrees, space group C2/c, Z = 8, rho(calcd) = 2.863 g/cm(3), R = 0.015; for II: a = 8.1855(4) angstrom, b = 21.509(1) angstrom, c = 8.7570(4) angstrom, beta = 106.891(1)degrees, space group P2(1)/c, Z = 4, rho(calcd) = 3.429 g/cm(3), R = 0.039; for III: a = 7.3660(5) angstrom, b = 8.3330(4) angstrom, c = 12.4914(7) angstrom, alpha = 104.719(2)degrees, beta = 95.674(3)degrees, gamma = 92.281(3)degrees, space group P-1, Z = 2, rho(calcd) = 3.636 g/cm(3), R = 0.061. The crystal structure of [Pd(Dien)Cl]Cl (IV) was established. The crystallographic data for IV: a = 13.935(3) angstrom, b = 4.823(1) angstrom, c = 13.249(3) angstrom, space group Pca2(1), Z = 4, rho(calcd) = 2.092 g/cm(3), R = 0.044. Intermolecular interactions (metal-halide ion, halogen-halogen) were revealed, which play an important role in constructing the general motif of crystal structures of compounds I-IV.

  DOI：

  10.1134/s0036023615050149

文献信息

• Synthesis and structure of double complex salts [Pd(Dien)Cl][AuX4] (X = Cl, Br), [Pd(Dien)Br][AuBr4], and initial complex [Pd(Dien)Cl]Cl
  作者：E. V. Makotchenko、I. A. Baidina、I. V. Korol’kov

  DOI：10.1134/s0036023615050149

  日期：2015.7

  New double complex salts were prepared: [Pd(Dien)Cl][AuCl4] (I), [Pd(Dien)Cl][AuBr4] (II), and [Pd(Dien)Br][AuBr4] (III). The compounds were studied by elemental analysis, IR spectroscopy, X-ray powder diffraction, and X-ray crystallography. Crystallographic data for I: a = 16.6661(5) angstrom, b = 12 7175(4) angstrom, c = 12.8936(4) angstrom, beta = 97.621(1)degrees, space group C2/c, Z = 8, rho(calcd) = 2.863 g/cm(3), R = 0.015; for II: a = 8.1855(4) angstrom, b = 21.509(1) angstrom, c = 8.7570(4) angstrom, beta = 106.891(1)degrees, space group P2(1)/c, Z = 4, rho(calcd) = 3.429 g/cm(3), R = 0.039; for III: a = 7.3660(5) angstrom, b = 8.3330(4) angstrom, c = 12.4914(7) angstrom, alpha = 104.719(2)degrees, beta = 95.674(3)degrees, gamma = 92.281(3)degrees, space group P-1, Z = 2, rho(calcd) = 3.636 g/cm(3), R = 0.061. The crystal structure of [Pd(Dien)Cl]Cl (IV) was established. The crystallographic data for IV: a = 13.935(3) angstrom, b = 4.823(1) angstrom, c = 13.249(3) angstrom, space group Pca2(1), Z = 4, rho(calcd) = 2.092 g/cm(3), R = 0.044. Intermolecular interactions (metal-halide ion, halogen-halogen) were revealed, which play an important role in constructing the general motif of crystal structures of compounds I-IV.