dibromobis(thiazole)copper(II) | 46142-46-5

• 英文名称: dibromobis(thiazole)copper(II)
• CAS: 46142-46-5
• 化学式: C₆H₆Br₂CuN₂S₂
• 分子量: 393.613
• InChiKey: XUXFFMQPMJSQPZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  dibromobis(thiazole)copper(II) 、 molybdenum hexacarbonyl 以 neat (no solvent, solid phase) 为溶剂， 生成 trans-tribromotris(1,3-thiazole-N)-molybdenum(III)
  参考文献：
  名称：

  trans-Tribromotris(1,3-thiazole-N)molybdenum(III)

  摘要：

  The title compound, [MoBr3(C3H3NS)(3)], has been synthesized by the solid-state reaction of Cu(thiazole)(2)Br-2 and Mo(Co)(6) under argon. A pseudo-octahedral Mo centre is formed by the N-bonded thiazole ligands and the Br ligands. The thiazole rings display orientational disorder due to 180 degrees rotations about their Mo-N bonds.

  DOI：

  10.1107/s0108270197007129
• 作为产物：
  描述：

  异噻唑 、 copper(ll) bromide 以 乙醇 为溶剂， 生成 dibromobis(thiazole)copper(II)
  参考文献：
  名称：

  Synthesis and crystal structure of the 1-dimensional dihalide-bridged polymers: dichlorobis(thiazole)iron(II) and dibromobis(thiazole)copper(II)

  摘要：

  The new polymeric compound Fe(thiazole)(2)Cl-2 (1) has been synthesised by the addition of thiazole to an ethanolic solution of anhydrous FeCl2. The structure of Cu(tz)(2)Br-2 (2) has also been determined. The structures of both polymers consist of pseudo-octahedral units, doubly linked by halide-bridges to form infinite linear chains. Slight variation in the bonding of the two are observed, relating to the Jahn-Teller nature of Cu2+. Room temperature magnetic susceptibility measurements of 1 give an effective moment of 5.51(2) B.M., indicating high-spin Fe(II). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00521-4