[Ru(2,2'-bipyridine)2(3,3'-bis(5,6-dimethyl)-1,2,4-triazine)2](2+) | 1240050-69-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: [Ru(2,2'-bipyridine)2(3,3'-bis(5,6-dimethyl)-1,2,4-triazine)2](2+)
• 英文别名: [Ru(bpy)2(btm)](2+)
• CAS: 1240050-69-4
• 化学式: C₃₀H₂₈N₁₀Ru
• 分子量: 629.689
• InChiKey: SEMYUHBKOHIKAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 3,3'-bis(5,6-dimethyl-1,2,4-triazine) 以 乙二醇 为溶剂， 生成 [Ru(2,2'-bipyridine)2(3,3'-bis(5,6-dimethyl)-1,2,4-triazine)2](2+)
  参考文献：
  名称：

  Temperature dependence of dual emission in ruthenium(II) complexes containing 3,3′-bi-1,2,4-triazine derivatives

  摘要：

  Three new ruthenium(II) polypyridyl complexes with highly pi-deficient ligands, [Ru(bpy)(2)(btm)](2+) (1), [Ru (bpy)(2)(btb)](2+) (2) and [Ru(bpy)(2)(btp)](2+) (3) (bpy = 2,2'-bipyridine, btm = 3,3'-bis(5,6-dimethyl-1,2,4-triazine, btb= 3,3'-bis(5,6-diphenyl-1,2,4-triazine, btp = 3,3'-bis(phenanthro[9,10-e][1,2,4]triazine) were synthesized and characterized. Electrochemical data together with molecular calculations show that the first redox process in these complexes is not bpy based. Complexes 1, 2 and 3 display luminescence in ethanol/methanol (4/1, V/V) at 80K, and all three complexes exhibit a temperature switch from single (150 K) to dual (80 K) emission behavior. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.05.019