bis[5-((4-dodecyloxyphenyl)azo)-N-ethanol salicylaldiminato]copper(II) | 902454-36-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: bis[5-((4-dodecyloxyphenyl)azo)-N-ethanol salicylaldiminato]copper(II)
• CAS: 902454-36-8
• 化学式: C₅₄H₇₆CuN₆O₆
• 分子量: 968.78
• InChiKey: PSADKNLQNUIITP-QCNYKUCUSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  5-(4-dodecyloxyphenylazo) salicylaldehyde 、 copper(II) acetate monohydrate 、 C.I.酸性橙108 以 乙醇 为溶剂， 以85%的产率得到bis[5-((4-dodecyloxyphenyl)azo)-N-ethanol salicylaldiminato]copper(II)
  参考文献：
  名称：

  Liquid crystalline properties of copper(II) complexes derived from azo-containing salicylaldimine ligands

  摘要：

  The one-step metal promoted reaction between 5+4-alkoxyphenyl)azo) salicylaldehyde (alkoxy = decyloxy, dodecyloxy, tetradecyloxy) and ethanolamine in the presence of Cu(CH3COO) center dot 4H(2)O yields new salicylaldimine based copper(II) bis(chelates) as a result of the [I + 1] Schiff base condensation. The liquid crystalline character of these complexes was examined using differential scanning calorimetry (DSC) and a polarizing microscope equipped with a heating and cooling stage. All copper complexes form the enantiotropic Smectic C mesophase. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.12.016