2,2,6,6-tetramethyl-4-(trimethylsilanyl-methyl)-2,4,6-trisila-heptan-4-ol | 18077-52-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2,2,6,6-tetramethyl-4-(trimethylsilanyl-methyl)-2,4,6-trisila-heptan-4-ol
• 英文别名: 2,2,6,6-Tetramethyl-4-(trimethylsilyl-methyl)-2,4,6-trisila-heptan-4-ol；Tris-trimethylsilylmethyl-silanol；Tris-(trimethylsilylmethyl)-silanol
• CAS: 18077-52-6
• 化学式: C₁₂H₃₄OSi₄
• 分子量: 306.743
• InChiKey: GYKAXZUWKIKALL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.56
• 重原子数：
  17.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  4-chloro-2,2,6,6-tetramethyl-4-(trimethylsilanyl-methyl)-2,4,6-trisila-heptane 在 三乙胺 作用下， 以 乙醚 、 水 为溶剂， 生成 2,2,6,6-tetramethyl-4-(trimethylsilanyl-methyl)-2,4,6-trisila-heptan-4-ol
  参考文献：
  名称：

  Reactivity studies of bridgehead organosilicon compounds with nucleophilic reagents

  摘要：

  DOI：

  10.1021/ja00804a026

文献信息

• Studies in Organosilicon Chemistry. XXXIV. The Reaction of Trimethylsilylmethyl Metallic Compounds with Trichlorosilane
  作者：BOBBY F. DANNELS、HOWARD W. POST

  DOI：10.1021/jo01358a008

  日期：1957.7
• Synthesis and characterization of mono-, bis-, tris- and tetrakis(trimethylsilylmethyl)silanes: (Me3SiCH2)xSiH4−x (x = 1−4)
  作者：Chris.K. Whitmarsh、Leonard V. Interrante

  DOI：10.1016/0022-328x(91)86347-s

  日期：1991.10

  The mono-, bis-, tris-, and tetrakis(trimethylsilylmethyl)silanes, (Me3SiCH2)(x)SiH4-x (x = 1-4), have been prepared for use as "models" of the various Si-centered functional units in a complex, highly branched polycarbosilane polymer of the approximate composition, "(SiH2CH2)n". These compounds have been characterized by GC, IR, H-1, C-13, Si-29 NMR, MS, and elemental analysis. The IR and NMR data for this series of compounds show distinct trends on increasing substitution, which are related to the structural differences within the series.