An intermediate in the reaction between trans-aquabis(ethylenediamine) sulphitocobalt(III) and sulphite ion in aqueous solution
作者:Sean M. Farrell、Robin S. Murray
DOI:10.1039/dt9770000322
日期:——
At 25 °C. pH 7.1, and I= 1.00 mol dm–3, the substitution reaction of trans-[Co(en)2(OH2)(SO3)]+ by [SO3]2– proceeds via the O-bonded intermediate trans-[Co(en)2(OSO2)(SO3)]– as follows: [Co(en)2(OH2)(SO3)]++[SO3]2– [graphic omitted] [Co(en)2(OH2)(SO3)][SO3]}–, [Co(en)2(OH2(SO3)][SO3]– [graphic omitted] [Co(en)2(OSO2)(SO3)]–+ H2O, [Co(en)2(OSO2)(SO3)]– [graphic omitted] [Co(en2(SO3)2]–, The values