N-(phenylazo)perhydroazepine | 1086224-46-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氮杂环庚烷
• 英文名称: N-(phenylazo)perhydroazepine
• CAS: 1086224-46-5
• 化学式: C₁₂H₁₇N₃
• 分子量: 203.287
• InChiKey: CLDIDPGYJHBBJA-BUHFOSPRSA-N

反应信息

• 作为反应物：
  描述：

  N-(phenylazo)perhydroazepine 以 乙腈 为溶剂， 反应 0.01h， 生成 N-(phenylazo)perhydroazepine
  参考文献：
  名称：

  动力学研究热顺至-反式的1- Phenyltriazenes异构化从环胺衍生

  摘要：

  热速率常数顺-到-反式的异构化ñ - （苯偶氮基） -取代的氮环heterocyles确定为苯基环取代的，环状胺环的大小，和有机溶剂的功能。发现观察到的一级速率常数随着对位取代基的吸电子特性的增加，胺环的增加以及溶剂极性的增加而增加。总体而言，观察到的趋势与通过极化过渡态围绕氮-氮双键旋转而发生的几何异构化相一致。

  DOI：

  10.1021/jo8024048
• 作为产物：
  描述：

  N-(phenylazo)perhydroazepine 以 乙腈 为溶剂， 生成 N-(phenylazo)perhydroazepine
  参考文献：
  名称：

  动力学研究热顺至-反式的1- Phenyltriazenes异构化从环胺衍生

  摘要：

  热速率常数顺-到-反式的异构化ñ - （苯偶氮基） -取代的氮环heterocyles确定为苯基环取代的，环状胺环的大小，和有机溶剂的功能。发现观察到的一级速率常数随着对位取代基的吸电子特性的增加，胺环的增加以及溶剂极性的增加而增加。总体而言，观察到的趋势与通过极化过渡态围绕氮-氮双键旋转而发生的几何异构化相一致。

  DOI：

  10.1021/jo8024048

文献信息

• UNSATURATED CYCLIC ANHYDRIDE END CAPPED POLYIMIDES AND POLYAMIC ACIDS AND PHOTOSENSITIVE COMPOSITIONS THEREOF
  申请人：PROMERUS, LLC

  公开号：US20200283580A1

  公开（公告）日：2020-09-10

  Embodiments in accordance with the present invention encompass polyamic acid or polyimide polymers containing a reactive unsaturated cyclic anhydride end group as well as photosensitive compositions made therefrom which are useful for forming films that can be patterned to create structures for microelectronic devices, microelectronic packaging, microelectromechanical systems, optoelectronic devices and displays. In some embodiments the compositions of this invention are shown to feature excellent hitherto unachievable mechanical properties. The negative images formed therefrom exhibit improved thermo-mechanical properties, among other property enhancements.
• POLYCYCLIC-OLEFINIC COMPOSITIONS FOR LOW-LOSS FILMS HAVING IMPROVED THERMAL PROPERTIES
  申请人：PROMERUS, LLC

  公开号：US20220135831A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers and at least one multifunctional olefinic monomer which when subjected to a suitable temperature undergoes mass polymerization to provide a three-dimensional insulating article which exhibits hitherto unattainable low dielectric constant and low-loss properties, and very high thermal properties. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. The compositions are stable at room temperature and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100° C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• SHELF LIFE STABLE AND IMPROVED MASS POLYMERIZABLE POLYCYCLIC-OLEFINIC COMPOSITIONS
  申请人：PROMERUS, LLC

  公开号：US20220135832A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers, optionally at least one multifunctional olefinic monomer and a suitable solvent, which exhibits long shelf life stability and undergoes mass polymerization only when subjected to a suitable temperature to provide a three-dimensional insulating articles. Embodiments of this invention exhibit hitherto unattainable properties, such as for example, low dielectric constant and low loss properties, and very high thermal properties, among others. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. In general the compositions are stable at room temperature for an extended period of time lasting up to a few weeks and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100° C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• [EN] SHELF LIFE STABLE AND IMPROVED MASS POLYMERIZABLE POLYCYCLIC-OLEFINIC COMPOSITIONS<br/>[FR] COMPOSITIONS OLÉFINIQUES POLYCYCLIQUES POLYMÉRISABLES EN MASSE À DURÉE DE CONSERVATION STABLE ET AMÉLIORÉES
  申请人：[en]PROMERUS, LLC

  公开号：WO2022094236A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers, optionally at least one multifunctional olefinic monomer and a suitable solvent, which exhibits long shelf life stability and undergoes mass polymerization only when subjected to a suitable temperature to provide a three- dimensional insulating articles. Embodiments of this invention exhibit hitherto unattainable properties, such as for example, low dielectric constant and low loss properties, and very high thermal properties, among others. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. In general the compositions are stable at room temperature for an extended period of time lasting up to a few weeks and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100 °C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.
• [EN] POLYCYCLIC-OLEFINIC COMPOSITIONS FOR LOW-LOSS FILMS HAVING IMPROVED THERMAL PROPERTIES<br/>[FR] COMPOSITIONS POLYCYCLIQUES-OLÉFINIQUES POUR DES FILMS À FAIBLE PERTE PRÉSENTANT DES PROPRIÉTÉS THERMIQUES AMÉLIORÉES
  申请人：[en]PROMERUS, LLC

  公开号：WO2022094232A1

  公开（公告）日：2022-05-05

  Embodiments in accordance with the present invention encompass compositions containing one or more polycycloolefinic monomers and at least one multifunctional olefinic monomer which when subjected to a suitable temperature undergoes mass polymerization to provide a three-dimensional insulating article which exhibits hitherto unattainable low dielectric constant and low-loss properties, and very high thermal properties. The compositions of this invention may additionally contain one or more organic or inorganic filler materials, which provide improved thermo-mechanical properties in addition to very low dielectric properties. The compositions are stable at room temperature and undergo mass polymerization only when subjected to suitable higher temperatures generally above 100 °C. The compositions of this invention are useful in various applications, including as insulating materials in millimeter wave radar antennas, among others.