Cd3(N,N'-[2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine]ethylenediamine)(NO3)6*CH3CN | 915199-22-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: Cd3(N,N'-[2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine]ethylenediamine)(NO3)6*CH3CN
• CAS: 915199-22-3
• 化学式: C₂H₃N*C₄₈H₃₈Cd₃N₂₆O₁₈
• 分子量: 1645.28
• InChiKey: IODIFGJMBMUDIR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  cadmium(II) nitrate tetrhydrate 、 乙腈 、 N,N'-(2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine)ethylenediamine 以 乙腈 为溶剂， 以33%的产率得到Cd3(N,N'-[2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine]ethylenediamine)(NO3)6*CH3CN
  参考文献：
  名称：

  Solvent control in the synthesis of Zn(II) and Cd(II) supramolecular compounds with N,N′-{2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine}ethylenediamine

  摘要：

  Four novel supramolecular materials ZnL(NO3)(2) (1), CdL(NO3)(2) (2), Zn3L(NO3)(6)center dot CH3CN (3) and Cd3L(NO3)(6)center dot CH3CN (4) have been prepared by the reaction of Zn(II) and Cd(II) nitrate with the ligand N,N'- (2,4-di-[(di-pyridin-2-yl)amine]-1,3,5-triazine) ethylene-diamine (L) using a solvothermal synthetic procedure under autogenous pressure. The solid-state structure of these coordination compounds has been tuned by the crystallisation solvent. In methanol, the mononuclear materials I and 2 are obtained while in acetonitrile, the trinuclear complexes 3 and 4 are formed. The structures of 1-3 have been elucidated by means of single-crystal diffraction. Complex 4 has been isolated as a microcrystalline powder for which the IR and elemental analyses are in agreement with a trinuclear formulation. (C) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2006.04.030