2-N-[2-[[4-[2-[[4,6-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-6-chloro-1,3,5-triazin-2-yl]-methylamino]ethyl]-4-N,6-N-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl]-2-N,4-N,6-N-trimethyl-1,3,5-triazine-2,4,6-triamine | 1228174-19-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-N-[2-[[4-[2-[[4,6-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-6-chloro-1,3,5-triazin-2-yl]-methylamino]ethyl]-4-N,6-N-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl]-2-N,4-N,6-N-trimethyl-1,3,5-triazine-2,4,6-triamine
• CAS: 1228174-19-3
• 化学式: C₁₇₃H₃₃₂ClN₄₁
• 分子量: 3022.27
• InChiKey: DETPKVQZSBOUEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  63.2
• 重原子数：
  215
• 可旋转键数：
  150
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  336
• 氢给体数：
  0
• 氢受体数：
  41

反应信息

• 作为产物：
  描述：

  三聚氯氰 、 N2,N2'-(((6-(methyl(2-(methylamino)ethyl)amino)-1,3,5-triazine-2,4-diyl)bis(methylazanediyl))bis(ethane-2,1-diyl))bis(N2-methyl-N4,N4,N6,N6-tetraoctyl-1,3,5-triazine-2,4,6-triamine) 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 以88%的产率得到2-N-[2-[[4-[2-[[4,6-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-1,3,5-triazin-2-yl]-methylamino]ethyl-methylamino]-6-chloro-1,3,5-triazin-2-yl]-methylamino]ethyl]-4-N,6-N-bis[2-[[4,6-bis(dioctylamino)-1,3,5-triazin-2-yl]-methylamino]ethyl]-2-N,4-N,6-N-trimethyl-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  收敛法合成三嗪基树枝状和树枝状大分子及其与四氟苯醌相互作用的研究

  摘要：

  开发了一种方便，有效和收敛的方法来制备基于三嗪的树枝状和树枝状聚合物。由外围区域中二辛基氨基部分的存在引起的空间位阻允许不使用保护和脱保护步骤而合成可溶性树突。三嗪基树状聚合物是通过N，N'-二甲基乙烷-1,2-二胺与树突以1：2的比例反应制备的。树枝状聚合物与四氟苯醌的相互作用导致在吸收光谱中出现新的宽频带，红移了大约180 nm。 树突-树状聚合物-会聚方法-三嗪-四氟苯醌

  DOI：

  10.1055/s-0030-1258220

文献信息

• Visible light-absorbing complex, triazine-based dendritic polymer, and organic photovoltiac device
  申请人：Lai Long-Li

  公开号：US20100137539A1

  公开（公告）日：2010-06-03

  A visible light-absorbing complex includes an electron acceptor and an electron donor, the electron donor having a triazine-based dendritic polymer formed of a core group (C) and branch groups, each of the branch groups being composed of terminal groups (P) and a triazine-based moiety group. The triazine-based dendritic polymer is represented by the following formula (I): wherein G indicates the generation number, “G-1” indicating the layer number of the branch groups, n being the number of the terminal groups, m being the number of the branch groups, wherein Z 1 is a divalent group containing O or N, and an atom of Z 1 bonding to the triazine group should be O or N; and wherein, when G is 1, the core group should be a triazine-based core group having a triazine ring, and an atom of each of the terminal groups bonding to the triazine ring should be O or N.