cis-amminedichloro(isopropylamine)platinum(II) | 174691-87-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: cis-amminedichloro(isopropylamine)platinum(II)
• 英文别名: azane;platinum(2+);propan-2-amine;dichloride
• CAS: 174691-87-3
• 化学式: C₃H₁₂Cl₂N₂Pt
• 分子量: 342.128
• InChiKey: DEWQXNOFFCMIKH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -5.48
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 ammonium oxalate 、 异丙胺 在 hydrochloric acid 作用下， 以 水 为溶剂， 生成 cis-amminedichloro(isopropylamine)platinum(II)
  参考文献：
  名称：

  cis-Amminedichloroisopropylamineplatinum(II) by X-ray powder diffraction analysis

  摘要：

  The title compound, [PtCl2(C3H9N)(NH3)], was obtained from potassium tetrachloroplatinate(II) by a two-step route. Ab initio crystal structure determination was carried out using X-ray powder diffraction techniques. Patterson and Fourier syntheses were used for the atom locations and the Rietveld technique for the final structure refinement. The Pt coordination is close to planar, with Cl atoms in a cis orientation. Molecules are combined into groups of two molecules, with antiparallel PtN2Cl2 planes and a shortest Pt center dot center dot center dot Pt distance of 3.42 angstrom. The molecule groups are packed in a parquet motif into corrugated layers parallel to ab. The molecules in the layers are linked by H-N center dot center dot center dot Cl hydrogen bonds.

  DOI：

  10.1107/s0108270106013503