[3-Methyl-4-[3-(4-prop-2-enoyloxyphenyl)propanoyloxy]phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate | 886230-27-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [3-Methyl-4-[3-(4-prop-2-enoyloxyphenyl)propanoyloxy]phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
• CAS: 886230-27-9
• 化学式: C₃₅H₃₆O₉
• 分子量: 600.665
• InChiKey: GKVGDINZMKRFLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  44
• 可旋转键数：
  21
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  114
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  (4-Hydroxy-2-methylphenyl) 3-(4-prop-2-enoyloxyphenyl)propanoate 、 Methylsulfonyl 4-(6-prop-2-enoyloxyhexoxy)benzoate 在 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 [3-Methyl-4-[3-(4-prop-2-enoyloxyphenyl)propanoyloxy]phenyl] 4-(6-prop-2-enoyloxyhexoxy)benzoate
  参考文献：
  名称：

  POLYMERIZABLE COMPOUND AND COMPOSITION CONTAINING THE POLYMERIZABLE COMPOUND

  摘要：

  公开号：

  EP1813594B1

文献信息

• POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLARIZED LIGHT-EMITTING COATING MATERIAL, NOVEL NAPHTHOLACTAM DERIVATIVE NOVEL COUMARIN DERIVATIVE, NOVEL NILE RED DERIVATIVE, AND NOVEL ANTHRACENE DERIVATIVE
  申请人：Kubota Yusuke

  公开号：US20130334461A1

  公开（公告）日：2013-12-19

  Provided are a polymerizable liquid crystal composition, a coating material, a medium, and a polarizing device each produced using a polymerizable liquid crystal compound and a colorant and each capable of producing polarized light suitable for polarizing devices, and also a novel naphtholactam derivative, a novel coumarin derivative, a novel Nile Red derivative, and a novel anthracene derivative each suitable for use as the colorant. Specifically provided are a polymerizable liquid crystal composition containing (A) at least one liquid crystal compound having a polymerizable functional group, (B) at least one colorant, and (C) a polymerization initiator, and a novel naphtholactam derivative of formula (IV′), a novel coumarin derivative of formula (VI′), a novel Nile Red derivative of formula (VII′), and a novel anthracene derivative of formula (VIII′) each suitable for use as the colorant (B).

  提供了一种可聚合的液晶组合物、涂料材料、介质和极化装置，每种都使用了聚合液晶化合物和颜料，并且能够产生适合于极化装置的偏振光，还提供了一种新型萘内酰胺衍生物、一种新型香豆素衍生物、一种新型尼罗红衍生物和一种新型蒽衍生物，每种都适用于用作颜料。具体提供了一种聚合液晶组合物，包含（A）至少一种具有聚合功能基团的液晶化合物，（B）至少一种颜料，和（C）聚合引发剂，以及一种适用于用作颜料（B）的新型萘内酰胺衍生物（IV′）, 一种新型香豆素衍生物（VI′）, 一种新型尼罗红衍生物（VII′）和一种新型蒽衍生物（VIII′）。
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY ELEMENT COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813A1

  公开（公告）日：2010-10-27

  A liquid crystal composition comprising 100 parts by mass of a nematic liquid crystal composition having negative dielectric anisotropy and 0.01 to 3 parts by mass of a polymerizable compound of general formula (I). On being irradiated with an energy ray, such as UV rays, the liquid crystal composition provides an LCD capable of high-speed response without undergoing reduction in reliability (voltage holding ratio). In formula (I), rings C1, C2, and C3 are each benzene, cyclohexane or naphthalene; M1 and M2 are each hydrogen or methyl; Z1 is a direct bond, -L1-, -L1O-, etc.; Z4 is a direct bond, -L2-, -OL2-, etc.; at least one of Z1 and Z4 is not a direct bond; L1 and L2 are each C1-C10 alkylene; when Z1=Z4, one or more hydrogen atoms of the rings C1, C2, and C3 are substituted; Z2 and Z3 are each a direct bond, an ester bond, etc.; p and q are each 0 or 1, provided that p+q≥1.

  一种液晶组合物，由 100 份（质量份）具有负介电各向异性的向列液晶组合物和 0.01 至 3 份（质量份）通式（I）的可聚合化合物组成。当受到能量射线（如紫外线）照射时，该液晶组合物可提供高速响应的液晶显示器，而不会降低可靠性（电压保持率）。 在式 (I) 中，环 C1、C2 和 C3 分别是苯、环己烷或萘；M1 和 M2 分别是氢或甲基；Z1 是直接键、-L1-、-L1O- 等；Z4 是直接键、-L2-、-OL2- 等。当 Z1=Z4 时，环 C1、C2 和 C3 的一个或多个氢原子被取代；Z2 和 Z3 各为直接键、酯键等；p 和 q 各为 0 或 1，条件是 p+q≥1。
• TRIFUNCTIONAL (METH)ACRYLATE COMPOUND AND POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND
  申请人：Adeka Corporation

  公开号：EP2261201A1

  公开（公告）日：2010-12-15

  A trifunctional (meth)acrylate compound of general formula (I) and a polymerizable composition containing the compound. The compounds (I) wherein rings A1, A2, and A3 are each benzene or naphthalene, with at least one of them being naphthalene or wherein X1, X2, and X3 are each -COO- or -OCO- are preferred. More preferably, ring A3 is naphthalene. Even more preferably, the compound is alone capable of retaining a liquid crystal phase at or below 30°C. wherein M1, M2, and M3 are each methyl, etc.; ring A1, A2, and A3 are each benzene, naphthalene, etc.; Z1, Z2, and Z3 are each C1-C6 alkyl, etc.; X1, X2, and X3 are each -COO-, -OCO-, etc.; Y1 and Y2 are each -L1-, etc.; Y3 is -L2-, etc.; L1 and L2 are each C1-C8 alkylene; a, b, and c are the numbers of the substituents on ring A1, A2, and A3, respectively, each being an integer of (2u+2) or smaller (u is the number of the 6-membered rings composing the substituted monocyclic or fused ring); at least one of a, b, and c is 1 or greater; p is an integer of 1 to 8; q and r are each an integer of 1 to 3; and s and t are each 0 or 1, satisfying (s+t≥1).

  通式(I)的三官能团(甲基)丙烯酸酯化合物和含有该化合物的可聚合组合物。优选环 A1、A2 和 A3 分别为苯或萘，其中至少一个为萘，或 X1、X2 和 X3 分别为 -COO- 或 -OCO- 的化合物 (I)。更优选的是，环 A3 是萘。更优选的是，该化合物能单独在 30°C 或以下保持液晶相。 其中 M1、M2 和 M3 各为甲基等；环 A1、A2 和 A3 各为苯、萘等；Z1、Z2 和 Z3 各为 C1-C6 烷基等；X1、X2 和 X3 各为-COO-、-OCO-等；Y1 和 Y2 各为-L1-等；Y3 为-L2-等。L1和L2各自为C1-C8亚烷基；a、b和c分别为环A1、A2和A3上取代基的数目，各自为（2u+2）或更小的整数（u为组成取代单环或融合环的6元环的数目）；a、b 和 c 中至少有一个大于等于 1；p 为 1 至 8 的整数；q 和 r 分别为 1 至 3 的整数；s 和 t 分别为 0 或 1，满足 (s+t≥1)。
• LIQUID CRYSTAL COMPOSITION COMPRISING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY ELEMENT USING SAID LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2502973A1

  公开（公告）日：2012-09-26

  Disclosed is a liquid crystal composition comprising a polymerizable compound represented by the following general formula (I) and a nematic liquid crystal composition having negative dielectric anisotropy (Δε). In the general formula, ring C1 represents a benzene-1,2,4-triyl group; rings C2 to C4 each represent a 1,4-phenylene group, a naphthalene-2,6-diyl group or the like; M1 to M3 each represent a hydrogen atom or a methyl group; Z1 and Z2 each represent a direct bond, -L1-, -L1O-, -L1O-CO-or the like; Z6 represents a direct bond, -L2-, -OL2-, -O-COL2- or the like, while at least any one of Z1, Z2 and Z6 is not a direct bond; L1 and L2 each represent a C1-10 alkylene group; Z3 to Z5 each represent a direct bond, an ester bond or the like; and p, q and r each represent 0 or 1, while 1 ≤ p+q+r ≤ 3.

  本发明公开了一种液晶组合物，该液晶组合物由以下通式（I）代表的可聚合化合物和具有负介电各向异性（Δε）的向列液晶组合物组成。通式中，环 C1 代表苯-1,2,4-三基；环 C2 至 C4 分别代表 1,4-苯基、萘-2,6-二基或类似基团；M1 至 M3 分别代表氢原子或甲基；Z1 和 Z2 分别代表直接键、-L1-、-L1O-、-L1O-CO-或类似键；Z6代表直接键、-L2-、-OL2-、-O-COL2-或类似物，而 Z1、Z2 和 Z6 中的至少任一个不是直接键； L1 和 L2 各自代表 C1-10 烷基； Z3 至 Z5 各自代表直接键、酯键或类似物；以及 p、q 和 r 各自代表 0 或 1，而 1≤p+q+r ≤3。
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813B1

  公开（公告）日：2015-11-04