The reaction of coarse-grain manganese powder with diiodotrimethylphosphorane to form [Mn(PMe3)I2] n , which reacts with trace quantities of molecular oxygen to form the mixed (+2/+3) oxidation state complex [Mn2(PMe3)3I5]PMe3
The X-ray crystal; structure of trans-tri-iodobis(trimethylphosphine)manganese(III). The first example of a trigonal bipyramidal manganese(III) tertiary phosphine complex
作者:Brian Beagley、Charles A. McAuliffe、Karl Minten、Robin G. Pritchard
DOI:10.1039/c39840000658
日期:——
The reaction of Mnl2(PMe3)with dioxygen leads to the formation of the trigonalbipyramidal bisphosphine manganese(III) complex, trans-Mnl3(PMe3)2; no phosphine oxidation is observed.