5-[[4-Amino-2-methyl-5-(3-sulfopropoxy)phenyl]diazenyl]benzene-1,3-dicarboxylic acid | 916851-93-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 5-[[4-Amino-2-methyl-5-(3-sulfopropoxy)phenyl]diazenyl]benzene-1,3-dicarboxylic acid
• CAS: 916851-93-9
• 化学式: C₁₈H₁₉N₃O₈S
• 分子量: 437.43
• InChiKey: BMFQFOZFSQWCEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  197
• 氢给体数：
  4
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  3-(2-氨基-4-甲基苯氧基)丙烷-1-磺酸 在 盐酸 、 sodium hydroxide 、 sodium nitrite 、 sodium carbonate 作用下， 以 水 为溶剂， 反应 2.0h， 生成 5-[[4-Amino-2-methyl-5-(3-sulfopropoxy)phenyl]diazenyl]benzene-1,3-dicarboxylic acid
  参考文献：
  名称：

  AZO COMPOUND, INK COMPOSITION, RECORDING METHOD AND COLORED MATTER

  摘要：

  本发明涉及一种偶氮化合物，由以下式（1）[KA1]表示（其中，R1和R2各自独立地表示氢原子，卤素原子，氰基，羧基，磺酰基，磺酰胺基或类似物，m和n各自独立地表示0或1，X表示磺酰基，B表示取代的对苯撑基或取代的对萘撑基（这些可以被从磺酰基，磺酰C1到C4烷氧基，C1到C4烷基等组成的群体中选择的群体取代），C表示取代的苯基或萘基）或其盐，以及包含它的墨水组成物，特别是黑色墨水组成物。所述五聚偶氮化合物在主要成分为水的介质中具有良好的溶解性，并适用于水溶性组合物（墨水组成物等）用于喷墨记录和书写工具;使用该组成物记录的文章在光牢度和臭氧气体牢度等方面具有优异性;记录图像上不会产生青铜色;其记录液在储存稳定性方面表现良好。

  公开号：

  EP1889882A1

文献信息

• TRISAZO COMPOUND, INK COMPOSITION, RECORDING METHOD AND COLORED MATTER
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP1975205B1

  公开（公告）日：2012-05-02
• Trisazo Compound, Ink Composition, Recording Method, and Colored Article
  申请人：Matsui Takahiko

  公开号：US20090062545A1

  公开（公告）日：2009-03-05

  The present invention relates to a trisazo compound represented by the following formula (1) or a salt thereof, The formula (1) (wherein, the group A is a substituted phenyl group, the group B and the group C are substituted para-phenylene groups, R 1 represents a C1 to C4 alkyl group (which may be substituted by a carboxy group), a phenyl group (which may be substituted by a sulfo group), or a carboxy group, R 2 represents a cyano group, a carbamoyl group or a carboxy group, each of R 3 and R 4 independently represents a hydrogen atom, a methyl group, a chlorine atom or a sulfo group, respectively) and a water-based black ink composition containing said compound; said compound has high solubility in a medium where the main component is water, its aqueous solution having a high concentration and ink are stable when stored for a long period of time, black-recorded images with it can be provided where both light fastness and ozone gas fastness of the printed images are excellent.
• Azo compound, ink composition, recording method and colored article
  申请人：Ohno Hiroaki

  公开号：US20090118479A1

  公开（公告）日：2009-05-07

  The present invention relates to an azo compound represented by the following formula (1) (wherein, each of R 1 and R 2 independently represents a hydrogen atom, a halogen atom, a cyano group, a carboxyl group, a sulfo group, a sulfamoyl group or the like, each of m and n independently represents 0 or 1, X represents a sulfo group, B represents a substituted p-phenylene group or a substituted p-naphthylene group (these may be substituted by a group selected from the group consisting of a sulfo group, a sulfo C1 to C4 alkoxy group, a C1 to C4 alkyl group and the like), and C represents a substituted phenyl group or a naphthyl group) or a salt thereof, an ink composition containing it, especially a black ink composition. Said pentakis-azo compound is excellent in solubility to medium whose main component is water and suitable for an water-soluble composition (ink composition and the like) for inkjet recording and writing tools; recorded articles recorded using said composition are excellent in fastnesses such as light fastness and ozone gas fastness; bronzing is not generated on the recorded images; and its recording liquids are good in storage stability.
• US8167991B2
  申请人：——

  公开号：US8167991B2

  公开（公告）日：2012-05-01
• AZO COMPOUND, INK COMPOSITION, RECORDING METHOD AND COLORED MATTER
  申请人：NIPPON KAYAKU KABUSHIKI KAISHA

  公开号：EP1889882A1

  公开（公告）日：2008-02-20

  The present invention relates to an azo compound represented by the following formula (1) [KA 1] (wherein, each of R1 and R2 independently represents a hydrogen atom, a halogen atom, a cyano group, a carboxyl group, a sulfo group, a sulfamoyl group or the like, each of m and n independently represents 0 or 1, X represents a sulfo group, B represents a substituted p-phenylene group or a substituted p-naphthylene group (these may be substituted by a group selected from the group consisting of a sulfo group, a sulfo C1 to C4 alkoxy group, a C1 to C4 alkyl group and the like), and C represents a substituted phenyl group or a naphthyl group) or a salt thereof, an ink composition containing it, especially a black ink composition. Said pentakis-azo compound is excellent in solubility to medium whose main component is water and suitable for an water-soluble composition (ink composition and the like) for inkjet recording and writing tools; recorded articles recorded using said composition are excellent in fastnesses such as light fastness and ozone gas fastness; bronzing is not generated on the recorded images; and its recording liquids are good in storage stability.

  本发明涉及一种偶氮化合物，由以下式（1）[KA1]表示（其中，R1和R2各自独立地表示氢原子，卤素原子，氰基，羧基，磺酰基，磺酰胺基或类似物，m和n各自独立地表示0或1，X表示磺酰基，B表示取代的对苯撑基或取代的对萘撑基（这些可以被从磺酰基，磺酰C1到C4烷氧基，C1到C4烷基等组成的群体中选择的群体取代），C表示取代的苯基或萘基）或其盐，以及包含它的墨水组成物，特别是黑色墨水组成物。所述五聚偶氮化合物在主要成分为水的介质中具有良好的溶解性，并适用于水溶性组合物（墨水组成物等）用于喷墨记录和书写工具;使用该组成物记录的文章在光牢度和臭氧气体牢度等方面具有优异性;记录图像上不会产生青铜色;其记录液在储存稳定性方面表现良好。