4,4',4''-次乙基三[N,N-二甲基-苯胺] | 23308-43-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 中文名称: 4,4',4''-次乙基三[N,N-二甲基-苯胺]
• 英文名称: 1,1,1-tris(4-N,N-dimethylaminophenyl)ethane
• 英文别名: 1,1,1-tris-(4-dimethylamino-phenyl)-ethane；1,1,1-Tris-(4-dimethylamino-phenyl)-aethan；Benzenamine,4,4',4''-ethylidynetris[N,N-dimethyl-；4-[1,1-bis[4-(dimethylamino)phenyl]ethyl]-N,N-dimethylaniline
• CAS: 23308-43-2
• 化学式: C₂₆H₃₃N₃
• 分子量: 387.568
• InChiKey: OMSLJDAHZGPUFL-UHFFFAOYSA-N

物化性质

• 熔点：
  176-178 °C(Solv: benzene (71-43-2); ethanol (64-17-5))
• 沸点：
  535.0±50.0 °C(Predicted)
• 密度：
  1.066±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 海关编码：
  2921590090

反应信息

• 作为反应物：
  描述：

  4,4',4''-次乙基三[N,N-二甲基-苯胺] 以 苯 为溶剂， 反应 9.0h， 生成 3-[1-(4-Dimethylamino-phenyl)-ethyl]-N⁴,N⁴,N^4',N^4'-tetramethyl-biphenyl-4,4'-diamine 、 4-[4-[4-(dimethylamino)phenyl]-1,4-dimethyl-2H-3,1-benzoxazin-6-yl]-N,N-dimethylaniline 、 4'-Dimethylamino-3-[1-(4-dimethylamino-phenyl)-1-hydroxy-ethyl]-biphenyl-4-ol 、 1-(4,4'-Bis-dimethylamino-biphenyl-3-yl)-1-(4-dimethylamino-phenyl)-ethanol
  参考文献：
  名称：

  三芳基甲烷染料亮腈的光化学和光物理。

  摘要：

  通过产物分析和俘获实验，激光闪光和稳态光解以及稳态荧光​​的方法研究了结晶紫晶腈（CVCN）的光化学反应。详细检查了氧气对反应的影响。研究了孔雀石绿亮腈（MGCN），碱性品红亮氨酸（BFCN），结晶紫亮氨乙基（CVMe）和亮氨苄基（CVBn）以及三苯基乙腈的光化学性质。结果表明电离从S1发生，而二-pi-甲烷反应是从T1开始的光化学途径。

  DOI：

  10.1021/jo000374a
• 作为产物：
  描述：

  溶剂紫9 在 甲基碘化镁 、 乙醚 、 甲苯 作用下， 生成 4,4',4''-次乙基三[N,N-二甲基-苯胺]
  参考文献：
  名称：

  Ginsburg, Zhurnal Obshchei Khimii, 1953, vol. 23, p. 1677,1680;engl.Ausg.S.1761,1764

  摘要：

  DOI：

文献信息

• CHROMOGENIC COMPOSITION, CHROMOGENIC CURABLE COMPOSITION, LITHOGRAPHIC PRINTING PLATE PRECURSOR, PLATEMAKING METHOD, AND CHROMOGENIC COMPOUND
  申请人：FUJIFILM Corporation

  公开号：EP2818522A1

  公开（公告）日：2014-12-31

  To provide a color-forming composition and a color-forming curable composition each of which forms high color upon exposure to light and has small fading after the color formation, and a lithographic printing plate precursor capable of undergoing on-press development, which forms high color upon exposure to light, which has a high plate inspection property, and which provides a lithographic printing plate of high printing durability. A color-forming composition containing (A) a radical generator, (B) a compound represented by formula (1) shown below and (C) a binder polymer, a color-forming curable composition further containing (E) a polymerizable compound, and a lithographic printing plate precursor comprising an image-recording layer containing the color-forming curable composition. wherein, in the formula (1), R1 represents a group which reacts with a radical generated from the radical generator (A) to be released and forms a dye after the release, and T represents a nitrogen-containing hetero ring.

  提供一种成色组合物和一种成色固化组合物，每种成色组合物在光照下都能形成较高的颜色，并且在成色后褪色较小，还提供一种能够进行印刷机显影的平版印刷版前体，这种平版印刷版前体在光照下能形成较高的颜色，具有较高的印版检查性能，并能提供具有较高印刷耐久性的平版印刷版。 一种成色组合物，含有(A)自由基发生器、(B)由下式(1)表示的化合物和(C)粘合剂聚合物；一种成色固化组合物，进一步含有(E)可聚合化合物；以及一种平版印刷板前体，包括含有成色固化组合物的图像记录层。 其中，在式 (1) 中，R1 代表与自由基发生器 (A) 生成的自由基反应并在释放后形成染料的基团，T 代表含氮杂环。
• Tertiary amine compound, photoelectric conversion element, and solar cell
  申请人：RICOH COMPANY, LTD.

  公开号：US10651390B2

  公开（公告）日：2020-05-12

  A tertiary amine compound is provided. The tertiary amine compound is represented by the following general formula (1): where each of Ar1 and Ar2 independently represents a benzene ring having an alkyl group or an alkoxy group, an unsubstituted benzene ring, a naphthalene ring having an alkyl group or an alkoxy group, or an unsubstituted naphthalene ring.

  提供了一种叔胺化合物。叔胺化合物由以下通式（1）表示： 其中 Ar1 和 Ar2 各自独立地代表具有烷基或烷氧基的苯环、未取代的苯环、具有烷基或烷氧基的萘环或未取代的萘环。
• Nesmejanow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1951, p. 708,709
  作者：Nesmejanow et al.

  DOI：——

  日期：——
• 228. Studies on hydrogen cyanide. Part XV. The action of hydrogen chloride on methyl cyanide
  作者：Leonard E. Hinkel、Glyn J. Treharne

  DOI：10.1039/jr9450000866

  日期：——
• Influences of support fibers on shapes of heptane/hexadecane droplets in reduced gravity
  作者：B. D. Shaw、M. J. Harrison

  DOI：10.1007/bf02881679

  日期：2002.12

  This paper describes analytical and experimental results related to the effects of support fibers on shapes of heptane/hexadecane mixture droplets (both burning and evaporating) in reduced gravity. The experimental results were obtained from large droplets (a few mm) investigated during the MSL-1 Flight of Spacelab. Theoretical (asymptotic) analyses are developed to predict droplet shapes. These analyses, which predict droplet shapes very well, illustrate important aspects of droplet shapes in a transparent fashion. The asymptotic theory shows that for small droplet-fiber contact angles, two spatial zones exist where droplet shapes behave differently. Away from a fiber a droplet is essentially spherical. As the fiber is approached, however deviations from spherical symmetry are significant. Previously developed analytical theory to predict macroscopic droplet shapes also compares well with experimental results. In addition, the experiments indicate that thin liquid films can form on support fibers. In the present experiments, these films apparently lead to transient formation of small droplets/bubbles on the support fibers at locations near the surface of a droplet.