silver zirconium | 37381-02-5

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: silver zirconium
• 英文别名: zirconium-silver；Silver--zirconium (1/1)；silver;zirconium
• CAS: 37381-02-5
• 化学式: AgZr
• 分子量: 199.092
• InChiKey: VYNIYUVRASGDDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  锆 、 silver zirconium 、 生成
  参考文献：
  名称：

  The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3

  摘要：

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.

  DOI：

  10.1016/0925-8388(93)90402-9
• 作为产物：
  描述：

  锆 、 银 以 melt 为溶剂， 生成 silver zirconium
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.C, 18.1.2, page 248 - 249

  摘要：

  DOI：

文献信息

• Enhancement of glass-forming ability and plasticity via alloying the elements having positive heat of mixing with Cu in Cu48Zr48Al4 bulk metallic glass
  作者：D. Cao、Y. Wu、X.J. Liu、H. Wang、X.Z. Wang、Z.P. Lu

  DOI：10.1016/j.jallcom.2018.10.396

  日期：2019.3

  Abstract Limited glass-forming ability (GFA) and room-temperature brittleness are currently critical challenges for the field of bulk metallic glasses (BMGs). Simultaneously enhancing GFA and plasticity is a central yet important research theme in this area. In contrast to the traditional wisdom, herein we report that addition of the elements with positive heat of mixing (PHM) into Cu-Zr-Al BMGs not

  摘要 有限的玻璃形成能力 (GFA) 和室温脆性是目前大块金属玻璃 (BMG) 领域面临的关键挑战。同时提高 GFA 和可塑性是该领域的一个中心而重要的研究主题。与传统观点相反，本文报告将具有正混合热 (PHM) 的元素添加到 Cu-Zr-Al BMG 中，不仅促进了玻璃的形成，而且增强了塑性。发现具有较小 PHM 值的元素具有较大的最佳剂量，并且由于具有增强的堆积密度的液相稳定和通过减慢原子重排使晶相不稳定而在增强 GFA 方面更有效。而且，由于增强的结构非均质性，添加具有中等 PHM 值的元素有利于塑性变形。已建立的成分-GFA-特性关系可用于通过将 PHM 元素合金化来设计具有增强的 GFA 和塑性的新型 BMG。
• The lead-zirconium system: binary phases and a series of interstitial compounds of the host Zr5Pb3
  作者：Young-Uk Kwon、John D. Corbett

  DOI：10.1016/0925-8388(93)90402-9

  日期：1993.1

  The Pb-Zr system contains the phases Zr(approximately 5.8)Pb (Cr3Si-type), Zr5Pb3 (Mn5Si3) and Zr5Pb4 (Ti5Ga4). Zr5Pb4 as a substoichiometric region above approximately 800-degrees-C, extending to about Zr5Pb3.65 at 1000-degrees-C. Reactive powder sintering in sealed Ta containers at 1000-1350-degrees-C is the most effective route for the synthesis of pure phases of both the binaries and the interstitial derivatives Zr5Pb3Z. Twenty examples of the latter were obtained with Z = Al, Si, P, S, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Ag, Cd, In, Sn, Sb, Te, (Pb), (second period Z were not investigated). Single crystals for Z = Al, Cd, Zn, Pb0.87, Pb0.94 were obtained by metal flux or vapor phase transport reactions, and the last three were quantified by X-ray crystallography. Volume trends as a function of group and period follow metal/covalent radii trends for Z fairly well.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.C, 18.1.2, page 248 - 249
  作者：

  DOI：——

  日期：——
• Karlsson, N., Acta Chemica Scandinavica (1947-1973), 1952, vol. 6, p. 1424 - 1430
  作者：Karlsson, N.

  DOI：——

  日期：——