| 155736-25-7

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• CAS: 155736-25-7
• 化学式: C₂H₈N₂*C₄CdN₄*Mn
• 分子量: 331.518
• InChiKey: QKLFKVINZXLJMY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  potassium tetracyanocadmate(II) 、 manganese(ll) chloride 在 ethylenediamine 、 ascorbic acide 作用下， 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Preparation and some properties of tetracyano complexes M(en)M′(CN)4 (M=Cd(II), Mn(II);M′=Ni(II), Cd(II))

  摘要：

  Two new tetracyano complexes of the composition MnenNi(CN)4 and MnenCd(CN)4 were prepared and identified. Their structure and properties were investigated by IR and UV-VIS spectroscopy, X-ray powder diffraction and by measuring magnetic moments. The results were confronted with the structure and properties of the compounds CdenNi(CN)4 and CdenCd(CN)4. The results of this study show a considerable similarity between these groups of compounds. The thermal behaviour of all the examined compounds was investigated derivatographically. The following order of thermal stability of the investigated complexes was observed: Cd-Cd(215-degrees-C) < Mn-Cd(250-degrees-C) < Cd-Ni(275-degrees-C) < Mn-Ni(310-degrees-C)

  DOI：

  10.1007/bf02547014