3-(1-Hydroxypropan-2-yloxy)-1,1,1,2-tetraphenylpropan-2-ol;phosphorous acid | 33774-78-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 3-(1-Hydroxypropan-2-yloxy)-1,1,1,2-tetraphenylpropan-2-ol;phosphorous acid
• CAS: 33774-78-6
• 化学式: C30H36O9P2
• 分子量: 602.5
• InChiKey: IOVFCWZOYWSNEA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.69
• 重原子数：
  41
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  171
• 氢给体数：
  8
• 氢受体数：
  9

文献信息

• Optical parts and sulfur-containing poly (thio)ester (co)polymer
  申请人：——

  公开号：US20030204030A1

  公开（公告）日：2003-10-30

  A poly(thio)ester (co)polymer which comprises a repeating structural unit represented by the formula (1-A) as an essential structural unit: 1 [wherein R 11 is a divalent aliphatic hydrocarbon group which may contain at least one sulfur atom in a sulfide group; R 12 is a mono- or poly-cyclic aliphatic or aromatic dicarboxylic acid residue; and X 11 and X 12 are each independently an oxygen atom or sulfur atom, and when X 11 and X 12 are the oxygen atoms, R 11 is a divalent aliphatic hydrocarbon group containing at least one sulfur atom in the sulfide group]; and an optical component obtainable by molding the poly(thio)ester (co)polymer. The poly(thio)ester (co)polymer is excellent in transparency and optical characteristics (e.g., a higher refractive index, higher Abbe number, and lower birefringence), and has also good mechanical characteristics and thermal characteristics, and further is excellent in melt fluidity and injection moldability.

  一种聚（硫）酯（共）聚合物，其包括由公式（1-A）表示的重复结构单元作为必要的结构单元：1 [其中，R11是一个双价的脂肪族碳氢基团，可以在硫化物基团中含有至少一个硫原子；R12是一个单环或多环的脂肪族或芳香族二羧酸残基；X11和X12分别是氧原子或硫原子，当X11和X12是氧原子时，R11是一个含有至少一个硫原子的双价脂肪族碳氢基团]；以及通过模塑聚（硫）酯（共）聚合物获得的光学组件。该聚（硫）酯（共）聚合物在透明度和光学特性（例如更高的折射率、更高的阿贝数和更低的双折射率）方面表现出色，同时具有良好的机械特性和热特性，并且在熔融流动性和注塑性方面表现出色。
• OPTICAL PARTS AND SULFUR-CONTAINING POLY(THIO)ESTER (CO)POLYMER
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1279692A1

  公开（公告）日：2003-01-29

  A poly(thio)ester (co)polymer which comprises a repeating structural unit represented by the formula (1-A) as an essential structural unit: [wherein R11 is a divalent aliphatic hydrocarbon group which may contain at least one sulfur atom in a sulfide group; R12 is a mono- or poly-cyclic aliphatic or aromatic dicarboxylic acid residue; and X11 and X12 are each independently an oxygen atom or sulfur atom, and when X11 and X12 are the oxygen atoms, R11 is a divalent aliphatic hydrocarbon group containing at least one sulfur atom in the sulfide group]; and an optical component obtainable by molding the poly(thio)ester (co)polymer. The poly(thio)ester (co)polymer is excellent in transparency and optical characteristics (e.g., a higher refractive index, higher Abbe number, and lower birefringence), and has also good mechanical characteristics and thermal characteristics, and further is excellent in melt fluidity and injection moldability.

  一种聚(硫)酯(共)聚合物，它包括由式(1-A)代表的重复结构单元作为基本结构单元： [其中 R11 是二价脂族烃基，该烃基可能在硫化物基团中至少含有一个硫原子；R12 是单环或多环脂族或芳香族二羧酸残基；X11和X12各自独立地为氧原子或硫原子，当X11和X12为氧原子时，R11为二价脂族烃基，在硫化物基团中至少含有一个硫原子]；以及通过模塑聚(硫)酯(共)聚合物可获得的光学成分。聚（硫代）酯（共）聚合物具有优异的透明度和光学特性（例如，较高的折射率、较高的阿贝数和较低的双折射），同时还具有良好的机械特性和热特性，而且还具有优异的熔体流动性和注塑成型性。
• METHOD FOR PRODUCING ALLOPHANATE GROUP-CONTAINING POLYISOCYANATE, URETHANE PREPOLYMER AND POLYURETHANE RESIN COMPOSITION
  申请人：Mitsui Chemicals Polyurethanes, Inc.

  公开号：EP1970394A1

  公开（公告）日：2008-09-17

  Polyurethane resin compositions include a urethane prepolymer with an active hydrogen group and a polyisocyanate, or a urethane prepolymer with an isocyanate group and an active hydrogen compound. The urethane prepolymers having an active hydrogen group or an isocyanate group are obtained by reacting an allophanate group-containing polyisocyanate with a side-chain hydrocarbon group of 5 or more carbon atoms and a bifunctional or polyfunctional active hydrogen compound. Particularly preferably, the allophanate group-containing polyisocyanate is obtained by reacting a C5 or higher carbon number compound having an alcoholic hydroxyl group and an organic diisocyanate, in the presence of an organic bismuth carboxylate and an organic phosphite triester. The polyurethane resin compositions are suited for use as adhesives for bonding low-polarity resin bases such as polyolefin films.

  聚氨酯树脂组合物包括带有活性氢基和多异氰酸酯的聚氨酯预聚物，或带有异氰酸酯基和活性氢化合物的聚氨酯预聚物。具有活性氢基或异氰酸酯基的聚氨酯预聚物是由含异氰酸酯基的多异氰酸酯与 5 个或更多碳原子的侧链烃基和双官能团或多官能团活性氢化合物反应而得。特别优选的是，在有机羧酸铋和有机亚磷酸三酯存在下，通过使具有醇羟基的 C5 或更高碳原子数化合物和有机二异氰酸酯反应得到含异氰酸酯基团的多异氰酸酯。这种聚氨酯树脂组合物适合用作粘合聚烯烃薄膜等低极性树脂基的粘合剂。
• Process for producing allophanate group-containing polyisocyanates, urethane prepolymers, and polyurethane resin compositions
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2520598A2

  公开（公告）日：2012-11-07

  Polyurethane resin compositions include a urethane prepolymer with an active hydrogen group and a polyisocyanate, or a urethane prepolymer with an isocyanate group and an active hydrogen compound. The urethane prepolymers having an active hydrogen group or an isocyanate group are obtained by reacting an allophanate group-containing polyisocyanate with a side-chain hydrocarbon group of 5 or more carbon atoms and a bifunctional or polyfunctional active hydrogen compound. Particularly preferably, the allophanate group-containing polyisocyanate is obtained by reacting a C5 or higher carbon_number compound having an alcoholic hydroxyl group and an organic diisocyanate, in the presence of an organic bismuth carboxylate and an organic phosphite triester. The polyurethane resin compositions are suited for use as adhesives for bonding low-polarity resin bases such as polyolefin films.

  聚氨酯树脂组合物包括带有活性氢基和多异氰酸酯的聚氨酯预聚物，或带有异氰酸酯基和活性氢化合物的聚氨酯预聚物。具有活性氢基或异氰酸酯基的聚氨酯预聚物是由含异氰酸酯基的多异氰酸酯与 5 个或更多碳原子的侧链烃基和双官能团或多官能团活性氢化合物反应而得。特别优选的是，在有机羧酸铋和有机亚磷酸三酯存在下，通过使具有醇羟基的 C5 或更高碳原子数化合物和有机二异氰酸酯反应得到含异氰酸酯基团的多异氰酸酯。这种聚氨酯树脂组合物适合用作粘合聚烯烃薄膜等低极性树脂基的粘合剂。
• METHOD FOR PRODUCING SYNTHETIC ISOPRENE POLYMER LATEX
  申请人：Zeon Corporation

  公开号：EP2980127A1

  公开（公告）日：2016-02-03

  The present invention is a method for producing a synthetic isoprene polymer latex (D), comprising the steps of: mixing and emulsifying (A) an aqueous dispersion comprising 0.1 to 5 wt% of a synthetic isoprene polymer and 0.1 to 20 wt% of a surfactant with (B) a solution of a synthetic isoprene polymer in an organic solvent, thereby producing (C) an emulsified and mixed solution; and then removing the organic solvent from (C) the emulsified and mixed solution.

  本发明是一种生产合成异戊二烯聚合物胶乳（D）的方法，包括以下步骤：将(A) 包含 0.1 至 5 wt% 合成异戊二烯聚合物和 0.1 至 20 wt% 表面活性剂的水分散液与(B) 合成异戊二烯聚合物在有机溶剂中的溶液混合并乳化，从而产生(C) 乳化混合溶液；然后从(C) 乳化混合溶液中去除有机溶剂。