boron dichloride | 179011-63-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: boron dichloride
• CAS: 179011-63-3
• 化学式: BCl₂
• 分子量: 83.0
• InChiKey: GKWKOCYSCDZTAX-UBSORLBESA-N

反应信息

• 作为产物：
  描述：

  硼烷 在 氯 作用下， 生成 boron dichloride
  参考文献：
  名称：

  卤素与激光烧蚀硼的反应：固体氩气中BXn的红外光谱（X = F，Cl，Br，I； n = 1，2，3）

  摘要：

  BX(n) (X = F, Cl, Br, I; n = 1, 2, 3) species were produced by the reaction of laser-ablated atomic boron with F2, Cl2, Br2, and I2, trapped in solid argon at 12 +/- 1 K, and characterized by infrared absorption spectroscopy. The relative band intensities observed for BX, BX2, and BX3 Species depended on the method of production. Enclosing the boron target inside a tube and codepositing boron atoms with halogen molecules enhanced the primary reaction products BX and BX2, whereas passing the halogen through the tube and coaxially mixing with atomic boron promoted the final reaction product BX3. Very low laser power favored the BX and BX2 radicals over the BX3 molecules. These studies provide further chemical evidence for the intermediate BX2 radicals.

  DOI：

  10.1021/j100121a008