trisilver(1+) | 12595-27-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物
• 英文名称: trisilver(1+)
• CAS: 12595-27-6
• 化学式: Ag₃
• 分子量: 323.605
• InChiKey: QRRXPKRAUQKHNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  silver trimer 以 neat (no solvent) 为溶剂， 生成 trisilver(1+)
  参考文献：
  名称：

  The relaxation from linear to triangular Ag3 probed by femtosecond resonant two-photon ionization

  摘要：

  We present extended NeNePo (negative to neutral to positive) measurements on the ultrafast dynamics in the ground state of neutral, mass-selected Ag3 molecules. A vibrational wave packet in the neutral molecule is created with an ultrashort laser pulse by photodetachment of the excess electron from the corresponding mass-selected anion. The subsequent molecular rearrangement is probed by photoionization after a selected time delay. Complementary to our previous investigations of this process, we now use two-photon photoionization via a resonant state in the probe step. Here, a bound–bound excitation to a well-known state followed by one-photon ionization is used instead of the nonresonant bound/free transition into the ionic continuum. Using radiation with wavelengths near 370 nm for resonant ionization, we observe a fast bending motion of the initially linear Ag3, followed by an ultrafast intramolecular vibrational energy redistribution, interpretable as an intramolecular collision process. The signal shows an apparent loss of vibrational coherence after the collision, which can be explained by the finite temperature of the anionic clusters in our experiment. Additionally, we describe a previously unknown resonance in the linear neutral molecule around 500 nm.

  DOI：

  10.1063/1.479382

文献信息

• Sputtering of Surfaces by Positive Ion Beams of Low Energy
  作者：Richard E. Honig

  DOI：10.1063/1.1723219

  日期：1958.3

  on the surface, partly atoms and molecules characteristic of the sample. Among the latter particles, neutrals were about 100 times more abundant than those emitted as positive ions. Rather low yields (about one sample atom per 100 incident ions with 400‐ev energy) and relatively high threshold energies (40–50 ev for an angle of 30° between beam and surface) are believed to be due to surface contamination

  银、锗和锗硅合金表面已经用惰性气体离子 Ne+、A+、Kr+ 和 Xe+ 轰击，能量在 30 到 400 ev 之间。在 Heil 型振荡电子源中获得了介于 1 到 10 μa/cm2 之间的初级光束强度。在 5.5 英寸半径的 180° 质谱仪中识别并记录溅射出的二次粒子、中性离子以及正离子和负离子。它们部分是吸附在表面的背景气体，部分是样品特征的原子和分子。在后一种粒子中，中性粒子的数量比作为正离子发射的粒子多约 100 倍。相当低的产率（每 100 个具有 400 ev 能量的入射离子大约有一个样品原子）和相对较高的阈值能量（40-50 ev，光束和表面之间的角度为 30°）被认为是由于表面污染。延迟电位测量表明，超过 80% 的溅射粒子具有小于 5 ev 的初始能量。经过...
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.A2, 18, page 152 - 154
  作者：

  DOI：——

  日期：——
• Mitric, Roland; Petersen, Jens; Kulesza, Alexander, Journal of Chemical Physics, p. 1 - 9
  作者：Mitric, Roland、Petersen, Jens、Kulesza, Alexander、Bonacic-Kouteck, Vlasta、Tabarin, Thibault、et al.

  DOI：——

  日期：——