Co(2-(2-hydroxyphenyl)-4,4-diphenyl-1,4-dihydro-2H-3,1-benzoxazine(-1H))2 | 923019-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: Co(2-(2-hydroxyphenyl)-4,4-diphenyl-1,4-dihydro-2H-3,1-benzoxazine(-1H))2
• CAS: 923019-50-5
• 化学式: C₅₂H₄₀CoN₂O₄
• 分子量: 815.894
• InChiKey: JKUUWZLJYOTKJC-WXXRPRERSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-(2-hydroxyphenyl)-4,4-diphenyl-1,2-dihydro-4H-3,1-benzoxazine 、 cobalt(II) acetate 以 乙醇 为溶剂， 以48%的产率得到Co(2-(2-hydroxyphenyl)-4,4-diphenyl-1,4-dihydro-2H-3,1-benzoxazine(-1H))2
  参考文献：
  名称：

  Synthesis and study of copper(II), nickel(II), and cobalt(II) complex compounds with dihydrobenzoxazine derivatives

  摘要：

  Complex compounds ML2 of copper(II), nickel(II), and cobalt(II) with 2-(2-hydroxy-5-nitrophenyl)-4,4-diphenyl-1,4-dihydro-2H-3,1-benzoxazine and 2-(2-hydroxyphenyl)-4,4-diphenyl-1,4-dihydro-2H-3,1-benzoxazine (HL) were prepared by electrochemical and chemical syntheses. The complex formation involves the azomethine form of the ligand and gives a six-membered chelate cycle comprising deprotonated phenol and azomethine groups. The coordination entity has a planar structure with trans arrangement of the nitrogen and oxygen atoms.

  DOI：

  10.1134/s1070363206040244