Germanium(II) and germanium(IV) compounds from elemental germanium
作者:P. Riviere、A. Castel、J. Satge、C. Abdennadher
DOI:10.1021/om00051a005
日期:1991.5
Divalent germanium derivatives (GeX2 and RGeX) were generated by direct reaction between germanium powder and various mercury(II) halides. Difluorogermylene was isolated by means of sublimation, while other halogermylenes (GeX2 and RGeX) were characterized by trapping cycloaddition or insertion reactions. Adducts and cycloadducts thus obtained have been either isolated or characterized by means of comparison (GC and NMR and mass spectroscopy) with authentic samples synthesized by other routes.