mer-[Co(diethylenetriamine)(NH3)2(OH2)](3+) | 68687-77-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: mer-[Co(diethylenetriamine)(NH3)2(OH2)](3+)
• 英文别名: fac-[Co(diethylenetriamine)(NH3)2(OH2)](3+)
• CAS: 68687-77-4
• 化学式: C₄H₂₁CoN₅O
• 分子量: 214.237
• InChiKey: JHWBYRATMMZZKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 unsym-fac-cis-di(ammine)chloro(diethylenetriamine)cobalt(III) tetrachlorozincate(II) 以 高氯酸 为溶剂， 生成 mer-[Co(diethylenetriamine)(NH3)2(OH2)](3+)
  参考文献：
  名称：

  Anionopentaaminecobalt(III) complexes with polyamine ligands 27. Activation volumes for spontaneous and Hg2+-assisted chloride release reactions

  摘要：

  Activation volumes (Delta V-not equal) for the spontaneous and Hg2+-assisted chloride release reactions from some [CoCl(N)(5)](2+) complexes have been estimated from the effect of pressure (5-150 MPa, I= 1.0 M HCIO4) on the reaction rates. Delta V-not equal data for the spontaneous aquation process are all small negative (-4 to -9 cm(3) mol(-1)) whereas for the Hg2+-assisted process, Delta V-not equal are small positive (+ 0.5 to + 3 cm(3) mol(-1)). The implications are discussed in terms of an interchange substitution mechanism.

  DOI：

  10.1016/s0020-1693(96)05482-5

文献信息

• Kinetics of mer to fac isomerisation of diethylenetriamine in some octahedral cobalt(Ill) complexes
  作者：D.A. House

  DOI：10.1016/s0020-1693(00)89049-0

  日期：1978.1