| 115777-42-9

• 分子结构分类: 有机化合物 - 有机盐
• CAS: 115777-42-9
• 化学式: C₂₄H₆₁P₄Pt₂
• 分子量: 863.803
• InChiKey: GVXHJNMMBSFGJN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 、
  参考文献：
  名称：

  Solid-state chemistry of molecular metal oxide clusters. Synthesis and lattice mobility of coordinatively unsaturated platinum cations in a microporous solid

  摘要：

  Metathetic reactions of (R3P)(2)PtH(CH3CN)(+) and PW12O403- yield [(R3P)(2)PtH(CH3CN)](3)PW12O40 (R = Ph, Et). Thermal desolvation of solid [(Ph3P)(2)PtH(CH3CN)](3)PW12O40 yields [(Ph3P)(2)PtH](3)PW12O40 which is thought to contain interstitial (Ph3P)(2)PtH+ ions, Quantitative loss of acetonitrile from [(Et3P)(2)PtH(CH3CN)](3)PW12O40 at 180 degrees C produces a material containing (Et3P)(2)PtH+ and (Et3P)(3)Pt-2-(mu-PEt2)(mu-H)Et+. Although the crystals lack permanent channels, exposure to (CH3CN)-C-13 vapor leads to extensive isotopic exchange. This is proposed to result from chemical microporosity of the solid.

  DOI：

  10.1016/s0020-1693(97)05507-2