Benzoic acid 4-{3-hydroxy-2-[2-methoxy-4-((E)-3-oxo-propenyl)-phenoxy]-propionyl}-2-methoxy-phenyl ester | 904914-50-7

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: Benzoic acid 4-{3-hydroxy-2-[2-methoxy-4-((E)-3-oxo-propenyl)-phenoxy]-propionyl}-2-methoxy-phenyl ester
• CAS: 904914-50-7
• 化学式: C₂₇H₂₄O₈
• 分子量: 476.483
• InChiKey: MAZYYLREAZCZGE-VOTSOKGWSA-N

反应信息

• 作为反应物：
  描述：

  Benzoic acid 4-{3-hydroxy-2-[2-methoxy-4-((E)-3-oxo-propenyl)-phenoxy]-propionyl}-2-methoxy-phenyl ester 在 sodium hydroxide 、 sodium tetrahydroborate 作用下， 生成 (+/-)-threo-guaiacylglycerol-β-O-4'-coniferyl ether 、 Acetic acid (1S,2R)-3-acetoxy-1-(4-acetoxy-3-methoxy-phenyl)-2-[4-((E)-3-acetoxy-propenyl)-2-methoxy-phenoxy]-propyl ester
  参考文献：
  名称：

  Revised structure for a neolignan from Brucea javanica

  摘要：

  On the basis of H-1 and C-13 NMR spectral comparison with natural and synthetic compounds, the neolignan isomers isolated from Brucea javanica for which unusual 8-O-6'-structures were proposed have been reassigned to the conventional 8-O-6'-structures (erythro and threo-guaiacylglycerol-beta-coniferyl ether), respectively. Thus far, there is no evidence for the existence of 8-O-6'-neolignans in nature. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(98)00449-x
• 作为产物：
  描述：

  Benzoic acid 4-{3-hydroxy-2-[2-methoxy-4-((E)-propenyl)-phenoxy]-propionyl}-2-methoxy-phenyl ester 在 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 生成 Benzoic acid 4-{3-hydroxy-2-[2-methoxy-4-((E)-3-oxo-propenyl)-phenoxy]-propionyl}-2-methoxy-phenyl ester
  参考文献：
  名称：

  Revised structure for a neolignan from Brucea javanica

  摘要：

  On the basis of H-1 and C-13 NMR spectral comparison with natural and synthetic compounds, the neolignan isomers isolated from Brucea javanica for which unusual 8-O-6'-structures were proposed have been reassigned to the conventional 8-O-6'-structures (erythro and threo-guaiacylglycerol-beta-coniferyl ether), respectively. Thus far, there is no evidence for the existence of 8-O-6'-neolignans in nature. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(98)00449-x