bis(perfluoro-7-methyloctyl)thiophosphinic acid | 500776-78-3

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(perfluoro-7-methyloctyl)thiophosphinic acid
• 英文别名: Bis(perfluoro-7-methyloctyl) phosphinothioic acid；bis[1,1,2,2,3,3,4,4,5,5,6,6,7,8,8,8-hexadecafluoro-7-(trifluoromethyl)octyl]-hydroxy-sulfanylidene-λ5-phosphane
• CAS: 500776-78-3
• 化学式: C₁₈HF₃₈OPS
• 分子量: 1018.18
• InChiKey: SWVPJGHJHKFTSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.8
• 重原子数：
  59
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  40

文献信息

• Fluorinated and halogenated phosphinic acids and their active metal derivatives
  申请人：——

  公开号：US20030189193A1

  公开（公告）日：2003-10-09

  Compounds of formula (I), methods of making and method of using (including optical compositions and devices) are provided. The compounds are 1 where A 1 is selected from O and S; A 2 is selected from —OH, —SH, and —OR 3 ; R f and R f1 can be the same or different, can be branched or unbranched, can be linked to form cyclic or extended structures, and are selected from halogenated alkyl, halogenated aryl, halogenated cyclic alkyl, halogenated arylalkyl, halogenated alkylaryl, halogenated polyether, halogenated thioether, halogenated ether thioether, halogenated aklyl amino groups, halogenated alkylene, halogenated silylene, halogenated siloxanes, halogenated silazanes, halogenated olefins, perfluorinated C 1-20 alkyl, perfuorinated C 1-6 alkyl C 1-10 alkyl ethers, n-C 8 F 17 , n-C 6 F 13 , n-C 4 F 9 , n-C 2 F 5 , (CF 3 ) 2 CF(CF 2 ) 4 , n-C 10 F 21 , n-C 12 F 25 , (CF 3 ) 2 CF(CF 2 ) 6 , and (CF 3 ) 2 CFO(CF 2 ) 2 ; and R 3 can be branched or unbranched and is selected from C 1-15 alkyl, C 3-15 aryl, C 4-15 alkylaryl, and C 4-15 arylalkyl. Wherein, (i) if R f and R f1 are the same and selected from n-C 2 F 5 , n-C 4 F 9 , n-C 6 F 13 , n-C 7 F 15 , and n-C 8 F 17 , then A 1 is not O; (ii) if R f and R f1 are the same and selected from n-C 2 F 5 , n-C 4 F 9 , n-C 6 F 13 , n-C 7 F 15 , and n-C 8 F 17 , then A 2 is not —OH; and (iii) if A 1 is O, and if R f and R f1 are the same and selected from n-C 6 F 13 , n-C 7 F 15 and n-C 8 F 17 , then A 2 is not —OCH 3 .

  提供了式（I）的化合物，制备方法和使用方法（包括光学组合物和器件）。这些化合物为1其中A1从O和S中选择；A2从—OH，—SH和—OR3中选择；Rf和Rf1可以相同也可以不同，可以是支链或非支链，可以连接形成环状或扩展结构，从卤代烷基，卤代芳基，卤代环烷基，卤代芳基烷基，卤代烷基芳基，卤代聚醚，卤代硫醚，卤代醚硫醚，卤代烷基氨基，卤代烷基烯，卤代硅烯，卤代硅氧烷，卤代硅氮烷，卤代烯烃，全氟C1-20烷基，全氟C1-6烷基C1-10烷基醚，n-C8F17，n-C6F13，n-C4F9，n-C2F5，（CF3）2CF(CF2)4，n-C10F21，n-C12F25，（ ）2CF(CF2)6和（ ）2CFO(CF2)2中选择；和R3可以是支链或非支链，从C1-15烷基，C3-15芳基，C4-15烷基芳基和C4-15芳基烷基中选择。其中，（i）如果Rf和Rf1相同且从n- ，n- ，n- ，n-C7F15和n- 中选择，则A1不是O；（ii）如果Rf和Rf1相同且从n- ，n- ，n- ，n- 和n- 中选择，则A2不是—OH；（iii）如果A1是O，且如果Rf和Rf1相同且从n- ，n- 和n- 中选择，则A2不是—OCH3。
• [EN] HALOGENATED PHOSPHINIC ACIDS AND THEIR ACTIVE METAL DERIVATIVES<br/>[FR] ACIDES PHOSPHINIQUES HALOGENES ET LEURS DERIVES METALLIQUES ACTIFS
  申请人：PHOTON X INC

  公开号：WO2003082884A1

  公开（公告）日：2003-10-09

  Compounds of formula (I), their preparation and compositions thereof for optical devices). The compounds are formula (I), where A1 is selected from O and S; A2 is selected from -OH, -SH, and OR3; Rf and Rf1 can be the same or different, can be branched or unbranched, and are selected from perfluorinated C1-20alkyl, perfluorinated C1-6alkyl C1-10alkyl ethers, n-C8F17, n-C6F13, n-C4F9, n-C2F5, (CF3)2CF(CF2)4, n-C10F21, n-C12F25,(CF3)2CF(CF2)6, and (CF3)2CFO(CF2)2; and R3 can be branched or unbranched and is selected from C1-15 alkyl, C3-15 aryl, C4-15alkylaryl, and C4-15 arylalkyl, wherein, (i) if Rf and Rf1 are the same and selected from n-C2F5, n-C4F9, n-C6F13, n-C7F15, and n-C8F17, then A1 is not O; (ii) if Rf and Rf1 are the same and selected from n-C2F5, n-C4F9, n-C6F13, n-C7F15, and n-C8F17, then A2 is not -OH; and (iii) if A1 is O, and if Rf and Rf1 are the same and selected from n-C6F13, n-C7F15 and n-C8F17, then A2 is not -OCH3.