m,m'-di[N-(p-phenylazobenzene)salicylaldeimine] | 787624-16-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: m,m'-di[N-(p-phenylazobenzene)salicylaldeimine]
• CAS: 787624-16-2
• 化学式: C₃₈H₂₈N₆O₂
• 分子量: 600.679
• InChiKey: ZYJDGPPGCJYWLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  46.0
• 可旋转键数：
  9.0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  114.62
• 氢给体数：
  2.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  m,m'-di[N-(p-phenylazobenzene)salicylaldeimine] 、 copper(II) acetate monohydrate 以 甲醇 、 乙醇 为溶剂， 以77%的产率得到[Cu(m,m'-di[N-(p-phenylazobenzene)]salicylaldeimine(-2H))](n)
  参考文献：
  名称：

  Synthesis and Characterization of Some Cobalt(II), Copper(II), and Nickel(II) Complexes with New Schiff Bases from the Reaction ofp‐Aminoazobenzene with Salicylaldehyde

  摘要：

  Two new Schiff bases have been synthesized by the reaction of p-aminoazobenzene with salicylaldehyde ((LH)-H-1) and the oxidative polycondensation product of (LH)-H-1 ((LH)-H-2,). The complexes of cobalt(II), copper(II), and nickel(II) with (LH)-H-1 and (LH2)-H-2 have been prepared. The ligands and their complexes have been characterized by elemental analyses, IR spectra, electronic absorption spectra, mass spectra, H-1 and C-13 NMR spectra, and magnetic susceptibility measurements. The thermal properties of all complexes have been studied by TG and DTA. The analytical data show that the metal to ligand ratio in the (LH)-H-1 complexes is I : 2. but in the (LH2)-H-2, complexes it is 1 : 1.

  DOI：

  10.1081/sim-120037512