Bis-cyclopentadienyldimethylsilyl-methan | 16230-09-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: Bis-cyclopentadienyldimethylsilyl-methan
• CAS: 16230-09-4
• 化学式: C₁₅H₂₄Si₂
• 分子量: 260.527
• InChiKey: IFRZLWWUBUYIKC-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Bis-cyclopentadienyldimethylsilyl-methan 在 正丁基锂 作用下， 以 正己烷 为溶剂， 生成
  参考文献：
  名称：

  Catalytic dehydrocoupling of PhSiH3 with bimetallic Ti and Zr complexes

  摘要：

  Bimetallic titanium and zirconium complexes with bridges (X) between Cp ligands were compared to Cp2MCl2 as catalysts in the presence of (BuLi)-Bu-n for the dehydrocoupling of PhSiH3 to polyphenylsilane. The monobridged bimetallic complexes developed were of the composition [mu-X(C5H4)(2)][CpMCl2](2) with X = Me2Si (M = Ti, Zr), Me2SiCH2SiMe2 (M = Ti) and Me2SiCH2CH2SiMe2 (M = Ti, Zr). The dibridged bimetallic complexes examined were of the type [mu,mu-(Me2Si)(2)(C5H3)(2)][Cp'TiCl2](2) (Cp' = Cp trans isomer, Cp' = Cp*, Irans and cis isomers). There was not a significant difference in the molecular weight of the polysilane produced from Cp2TiCl2 and the bimetallic titanium complexes after 48 h of reaction. However, the polysilane which was generated from the bimetallic complex [mu-(Me2Si)(C5H4)(2)][CpZrCl2](2) was approximately twice the molecular weight compared to that obtained from Cp2ZrCl2. The structure of the bimetallic complex [mu-(Me2SiCH2CH2SiMe2)(C5H4)(3)][CpZrCl2](2) was determined by X-ray diffraction (monoclinic, P2(1)/n, a = 8.7297(3)Angstrom, b = 6.7890(2) Angstrom, c = 24.9343(7) Angstrom, beta = 93.7850(10)degrees, Z = 2).

  DOI：

  10.1016/s0022-328x(96)06825-8