(di(3-aminopropyl)amine)trichloro cobalt(III) | 15555-49-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: (di(3-aminopropyl)amine)trichloro cobalt(III)
• CAS: 15555-49-4；131485-81-9；75918-15-9
• 化学式: C₆H₁₇Cl₃CoN₃
• 分子量: 296.573
• InChiKey: HJZBYEPADXCSMM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (di(3-aminopropyl)amine)trichloro cobalt(III) 在 diethylenetriamine 作用下， 以 not given 为溶剂， 生成 钴三乙烯四胺络合物
  参考文献：
  名称：

  X-ray structure of Mer-Trichloro[N-(3-aminopropyl)-1,3-diaminopropane]cobalt(III)

  摘要：

  DOI：

  10.1016/s0020-1693(00)88925-2
• 作为产物：
  描述：

  (di(3-aminopropyl)amine)trisnitrocobalt(III) 在 (NH₂)2CO 、 HCl 作用下， 以 盐酸 为溶剂， 以96%的产率得到(di(3-aminopropyl)amine)trichloro cobalt(III)
  参考文献：
  名称：

  Searle, Graeme H.; Hambley, Trevor W., Australian Journal of Chemistry, 1982, vol. 35, p. 1297 - 1310

  摘要：

  DOI：

文献信息

• Preparation and Characterization of [Co₂(bidentate-<i>N</i>,<i>S</i>)₃(triamine)]-Type S-Bridged Dinuclear Complexes
  作者：Takumi Konno、Ken-ichi Okamoto、Jinsai Hidaka

  DOI：10.1246/bcsj.63.3027

  日期：1990.10

  Three kinds of S-bridged dinuclear complexes, Δ- and Λ-[Co2(aet)3(dien)]3+ (aet=2-aminoethanethiolate and dien=diethylenetriamine), Δ- and Λ-[Co2(aet)3(dpt)]3+ (dpt=bis(3-aminopropyl)amine)), and ΔLLL-[Co2(l-cys-N,S)3(dien)] (l-cys=l-cysteinate), were prepared by the reactions of [Co(aet)3] or ΔLLL-[Co(l-cys-N,S)3]3− with [CoCl3(dien)] or [CoCl3(dpt)]. The isomers were characterized from their absorption, CD, and 13C NMR spectra.

  三种S桥双核配合物，Δ-和Λ-[Co2(aet)3(dien)]3+（aet=2-氨基乙硫醇和dien=二乙烯三胺），Δ-和Λ-[Co2(aet)3( dpt)]3+ (dpt=双(3-氨基丙基)胺))和ΔLLL-[Co2(l-cys-N,S)3(dien)] (l-cys=l-半胱氨酸)，通过以下方法制备[Co(aet)3] 或 ΔLLL-[Co(l-cys-N,S)3]3− 与 [CoCl3(dien)] 或 [CoCl3(dpt)] 的反应。通过吸收光谱、CD 光谱和 13C NMR 光谱对异构体进行了表征。
• The phenomenon of conglomerate crystallization
  作者：Hyungphil Chun、Salah S. Massoud、Ruiwu Wen、Ivan Bernal

  DOI：10.1016/s0277-5387(99)00304-6

  日期：1999.12

  The X-ray structure analysis of mer-trans-[Co(aepn)Cl-2(OH2)](ClO4). H2O (1) (aepn =N-(2-aminoethyl)-1,3 -propanediamine) reveals that the compound crystallizes in an enantiomorphic space group P2(1)2(1)2(1) implying a spontaneous resolution of its racemic solution, known as conglomerate crystallization. Substitutions of the two chloride ligands with bromides result in the isostructural compound mer-trans-[Co(aepn)Br-2(OH2)](ClO4). H2O (2), which also crystallizes as a conglomerate in the space group P2(1)2(1)2(1). Meanwhile, a substitution of the coordinated OH2 of 1 with NH3 gives mer-trans-[Co(aepn)Cl-2(NH3)](ClO4) (3), which crystallizes as a simple racemate in P2(1)/n space group. When N-(3-aminopropyl)-1,3-propanediamine (dpt) is used instead of aepn in the preparation of 1, it gives racemic crystals of mer-trans-[Co(dpt)Cl-2(OH2)](ClO4) (4) whose molecular packing pattern is identical to that of 3. fn the conglomerate structures, the protons of coordinated water ligand are strongly hydrogen-bonded to the oxygen of a water of crystallization to form a spiral packing structures. In the packing structures of 3 and 4, two molecules of opposite chirality are brought together around a crystallographic center of inversion by hydrogen bonds of the protons of the corresponding tridentate amine ligand with oxygens of perchlorate anion. (C) 1999 Elsevier Science Ltd. All rights reserved.
• Neves, Ademir; Herrmann, Willy; Wieghardt, Karl, Inorganic Chemistry, 1984, vol. 23, # 22, p. 3435 - 3443
  作者：Neves, Ademir、Herrmann, Willy、Wieghardt, Karl

  DOI：——

  日期：——
• Triazidocobalt(III) complexes with tridentate amine ligands
  作者：Hyungphil Chun、Ivan Bernal

  DOI：10.1107/s0108270100011793

  日期：2000.11.15

  The title compounds, [N-(2-aminoethyl)-1,3-propanediamine- kappa N-3]triazidocobalt(III), [Co(N-3)(3)(C5H15N3)], [N-(2-aminoethyl)-N-methyl-1,3-propanediamine-kappa N-3]triazidocobalt(III), [Co(N-3)(3)(C6H17N3)], [N-(2-aminopropyl)-1,3-propanediamine-kappa (3) N]triazidocobalt(III), [Co(N-3)(3)(C6H17N3)], and [N-(2-aminopropyl)-N-methyl-1,3-propanediamine-kappa N-3]triazidocobalt(III), [Co(N-3)(3)(C7H19N3)], each consist of a Co-III atom, three azide ligands in a meridional configuration and a tridentate amine ligand, namely aepn [N-(2-aminoethyl)-1,3-propanediamine] or dpt [N-(3-aminopropyl)-1,3-propanediamine], or their N-methylated analogs.
• Massoud, S. S., Bulletin de la Societe Chimique de France, 1990, # 4, p. 496 - 502
  作者：Massoud, S. S.

  DOI：——

  日期：——