Trichloroiron;tetrahydrate | 16743-21-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Trichloroiron;tetrahydrate
• 英文别名: trichloroiron;tetrahydrate
• CAS: 16743-21-8
• 化学式: Cl*Cl₂FeH₈O₄
• 分子量: 234.267
• InChiKey: SBZZSNLTVKKWRQ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -1.23
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  吡啶 、 Trichloroiron;tetrahydrate 生成 trichlor tripyridine iron (III) (monopyridine)
  参考文献：
  名称：

  FeCl 2 py 4 + catalyzed transformation of aromatic amines by HOOH under mild conditions

  摘要：

  FeCl(2)py(4)(+) is capable of activating HOOH for the selective and efficient (yields range roughly from 50 to 80%) transformation of anilines at room temperature using pyridine as the solvent. Initially, aniline yields mainly nitrosobenzene that in turn reacts with more aniline to form the corresponding azo and azoxybenzene derivatives. Replacing HOOH by t-BuOOH in the system, changes the product distribution dramatically forming only nitrobenzene. Under the same conditions FeCl(2)py(4)(+) efficiently catalyzes the mono-demethylation of N,N'-dimethylaniline by HOOH. (C) 1999 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(99)00057-6

文献信息

• FeCl 2 py 4 + catalyzed transformation of aromatic amines by HOOH under mild conditions
  作者：Miquel Costas、Isabel Romero、Ma.Angeles Martı́nez、Antoni Llobet、Donald T. Sawyer、Josep Caixach

  DOI：10.1016/s1381-1169(99)00057-6

  日期：1999.12

  FeCl(2)py(4)(+) is capable of activating HOOH for the selective and efficient (yields range roughly from 50 to 80%) transformation of anilines at room temperature using pyridine as the solvent. Initially, aniline yields mainly nitrosobenzene that in turn reacts with more aniline to form the corresponding azo and azoxybenzene derivatives. Replacing HOOH by t-BuOOH in the system, changes the product distribution dramatically forming only nitrobenzene. Under the same conditions FeCl(2)py(4)(+) efficiently catalyzes the mono-demethylation of N,N'-dimethylaniline by HOOH. (C) 1999 Elsevier Science B.V. All rights reserved.