| 137031-76-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• CAS: 137031-76-6
• 化学式: BF₄*C₄H₁₁OS
• 分子量: 194.001
• InChiKey: GAHSHQHNXRSPPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  11.0
• 可旋转键数：
  1.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  铜 、 在 CH₃CN 作用下， 以 乙腈 为溶剂， 生成 tetrakis(acetonitrile)copper(I)tetrafluoroborate
  参考文献：
  名称：

  Simulation of donor-acceptor electron-transport systems in the example case of the oxidation of copper in media of organic solvents

  摘要：

  The interaction of the onium salts [Me2S+Et = O]Bf4-, [Me2N+ = CH-OEt]BF4-, and [Me3S+ = O]I- with metallic copper in DMSO, DMF, and acetonitrile (AN) has been investigated. It has been shown that the reaction takes place with an intermediate step involving the formation of Cu(I) compounds. The complexes [Cu(I)(AN)4]BF4, [Cu(II)(DMSO)5](BF4)2, [Cu(II)(DMSO)4(AN)2](BF4)2, [Cu(II)(DMSO)2(DMF)(AN)](BF4)2, and [Me3S+]3Cu(I)I4.[Me3S+ = O]I- have been isolated and characterized. It has been established that dipolar onium compounds which simulate the intermediate products of the interaction of the components of donor-acceptor electron-transport systems are responsible for the oxidation of metals in organic complex-forming media.

  DOI：

  10.1007/bf00961290