3-formyl-1-phenylene-(3,5-di-tert-butylbenzoate) | 1352282-93-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 3-formyl-1-phenylene-(3,5-di-tert-butylbenzoate)
• CAS: 1352282-93-9
• 化学式: C₂₂H₂₆O₃
• 分子量: 338.447
• InChiKey: SZZKBBOOMWWQNE-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  3-formyl-1-phenylene-(3,5-di-tert-butylbenzoate) 、 环己酮 在 L-AMP 、 HAC 作用下， 以 甲醇 、 水 为溶剂， 反应 168.0h， 生成
  参考文献：
  名称：

  “Click” post-synthetic modification of metal−organic frameworks for asymmetric aldol catalysis

  摘要：

  The reaction of dimethyl 5-(prop-2-ynyloxy)isophthalic acid, meso-alpha, and beta-di (4-pyridyl) glycol with ZnCl2 in a methanol aqueous solution affords MOF Zn-DPPG. The enantiomeric Zn-Fun1 and Zn-Fun2 were obtained through a strategy of in situ click reactions of Zn-DPPG with two opposite chiral adducts. With the L- or D-proline chiral functionality, the two Zn-Funs exhibited remarkable catalytic activities in the relative asymmetric aldol reactions, leading to the formation of opposite enantiomorphs, respectively. (C) 2013 Published by Elsevier B.V.

  DOI：

  10.1016/j.inoche.2013.10.031

文献信息

• Novel Isopolyoxotungstate [H₂W₁₁O₃₈]^8–Based Metal Organic Framework: As Lewis Acid Catalyst for Cyanosilylation of Aromatic Aldehydes
  作者：Qiuxia Han、Xueping Sun、Jie Li、Pengtao Ma、Jingyang Niu

  DOI：10.1021/ic5004879

  日期：2014.6.16

  chain. Adjacent 1D chains are linked through Cu(1)–bpy–Cu(2) in an opposite direction to form a two-dimensional (2D) wavelike sheet along the ab plane. These 2D sheets are further stacked in a parallel fashion giving rise to the 1D channels with copper(II) cations aligned in the channels. The resulting POMOF acted as a Lewis acid catalyst through a heterogeneous manner to prompt cyanosilylation with excellent

  一种新型的基于多金属氧酸盐的金属有机骨架（POMOF），由分离的异多氧钨酸盐[H 2 W 11 O 38 ] 8-团簇Cu 2（bpy）（H 2 O）5.5 ] 2 [H 2 W 11 O 38 ]构成·3H 2 O·0.5CH 3 CN}（1，其中bpy = 4,4'-bpydine）在溶剂热条件下合成，并通过元素分析，红外光谱和单晶X射线衍射表征。在1中，W 11 }簇由两个[Cu（2）（H2 O）1.5（O t）3（N）] 2+阳离子以意想不到的端对端方式生成一维（1D）链。相邻的一维链通过Cu（1）–bpy–Cu（2）沿相反方向链接，从而沿ab平面形成二维（2D）波浪状薄片。这些2D薄片以平行方式进一步堆叠，从而形成一维通道，其中铜（II）阳离子在通道中对齐。所得的POMOF通过非均相方式充当路易斯酸催化剂，以优异的效率促进氰基硅烷化。
• An l-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions
  作者：Xiao Wu、Cheng He、Xiang Wu、Siyi Qu、Chunying Duan

  DOI：10.1039/c1cc11698c

  日期：——

  incorporating a L-proline moiety within the corresponding ligand. Co-Pro1 comprised L-proline moieties as asymmetric catalytic active sites and a helical-like cavity, it worked as an asymmetric catalyst to prompt aldol reactions with size-, stereo- and enantioselectivity.

  通过将L-脯氨酸部分掺入相应的配体中，通过自组装获得了同手性​​金属-有机三角形Co-Pro1。Co-Pro1包含L-脯氨酸部分作为不对称的催化活性位点和一个螺旋状的腔，它作为不对称的催化剂来促进羟醛的反应，具有大小，立体和对映选择性。