2-morpholino-4-hydrazino-6-dinitromethyl-1,3,5-triazine | 1445907-97-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 2-morpholino-4-hydrazino-6-dinitromethyl-1,3,5-triazine
• CAS: 1445907-97-0
• 化学式: C₈H₁₂N₈O₅
• 分子量: 300.234
• InChiKey: BKLAAFLGVOKELO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  2-morpholino-4-hydrazino-6-dinitromethyl-1,3,5-triazine 在 potassium hydroxide 作用下， 以 甲醇 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  Synthesis and structure elucidation of novel 5-dinitromethyl-7-alkylamino-1,2,4-triazolo[4,3-a]-1,3,5-triazines

  摘要：

  Synthesis of the novel potassium salts of 5-dinitromethyl-7-alkylamino-1,2,4-triazolo[4,3-a]-1,3,5-triazines 9a-c was performed by heating (in DMSO) 2-alkylamino-4-ethoxymethylidenehydrazino-6-dinitromethyl-1,3,5-triazines 8a-c, obtained by treating of the corresponding 2-alkylamino-4-hydrazino-6-dinitromethyl-1,3,5-triazines 5a-c with orthoformic ester. 2-Alkylamino-4-hydrazino-6-dinitromethyl-1,3,5-triazines were obtained by a sequential substitution of the methoxy groups of the potassium salt of 2,4-dimethoxy-6-dinitromethyl-1,3,5-triazine with an alkylamine (dimethylamine, morpholine, pyrrolidine) and hydrazine. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.05.052
• 作为产物：
  描述：

  在 盐酸 作用下， 以 水 为溶剂， 反应 1.0h， 以89%的产率得到2-morpholino-4-hydrazino-6-dinitromethyl-1,3,5-triazine
  参考文献：
  名称：

  Synthesis and structure elucidation of novel 5-dinitromethyl-7-alkylamino-1,2,4-triazolo[4,3-a]-1,3,5-triazines

  摘要：

  Synthesis of the novel potassium salts of 5-dinitromethyl-7-alkylamino-1,2,4-triazolo[4,3-a]-1,3,5-triazines 9a-c was performed by heating (in DMSO) 2-alkylamino-4-ethoxymethylidenehydrazino-6-dinitromethyl-1,3,5-triazines 8a-c, obtained by treating of the corresponding 2-alkylamino-4-hydrazino-6-dinitromethyl-1,3,5-triazines 5a-c with orthoformic ester. 2-Alkylamino-4-hydrazino-6-dinitromethyl-1,3,5-triazines were obtained by a sequential substitution of the methoxy groups of the potassium salt of 2,4-dimethoxy-6-dinitromethyl-1,3,5-triazine with an alkylamine (dimethylamine, morpholine, pyrrolidine) and hydrazine. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.05.052