(6-trimethylsilylpyridine-2-selenolato-Se,N)copper(I) | 220559-25-1

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (6-trimethylsilylpyridine-2-selenolato-Se,N)copper(I)
• CAS: 220559-25-1
• 化学式: C₈H₁₂NSeSi*Cu
• 分子量: 292.781
• InChiKey: JBBXWNIKTYFFBA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.42
• 重原子数：
  12.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  12.89
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为产物：
  描述：

  、 铜 以 乙腈 为溶剂， 生成 (6-trimethylsilylpyridine-2-selenolato-Se,N)copper(I)
  参考文献：
  名称：

  Electrochemical synthesis of copper and silver pyridine-2-selenolato complexes: crystal structure of (6-trimethylsilylpyridine-2-selenolato)silver(I), [Ag6(6-Me3SipySe)6]

  摘要：

  (Pyridine-2-selenolato-Se, N)copper(I) and silver(I) [Cu(pySe)] and [Ag(pySe)] and (6-trimethylsilylpyridine-2-selenolato-Se, N)copper(I) and silver(I), [Cu(6-Me(3)SipySe)] and [Ag-6(6-Me(3)SipySe)(6)], were obtained by electrochemical oxidation of metals in an acetonitrile solution of the corresponding dimer diselenide ligands. The crystal structure of (6-trimethylsilylpyridine-2-selenolato)silver(I) has been determined by X-ray diffraction. The [Ag-6(6-Me(3)SipySe)(6)] compound is an hexamer with the six silver atoms arranged in a distorted octahedral geometry; each silver atom is trigonally coordinated to one nitrogen and two selenium atoms of three different ligands. Crystal data: triclinic, P-1, a = 9.700(2), b = 14.441(3), c = 14.495(3) Angstrom, alpha = 109.25(3), beta = 104.97(3), gamma = 101.34(3)degrees, V = 1761.2(6) Angstrom(3), Z = 6, D-calc = 1.907 g cm(-3), R = 0.0305 for 2729 reflections. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00280-1