c-hexyldiiodophosphane | 24547-24-8

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: c-hexyldiiodophosphane
• 英文别名: Cyclohexyl-diiod-phosphin；Cyclohexyldiiodophosphin；cyclohexyl(diiodo)phosphane
• CAS: 24547-24-8
• 化学式: C₆H₁₁I₂P
• 分子量: 367.936
• InChiKey: AJVISVNMKIQPAA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  c-hexyldiiodophosphane 在 selenium 作用下， 以 甲苯 为溶剂， 生成 c-hexyldiiodophosphane selenide
  参考文献：
  名称：

  Iodophosphane Selenides: Building Blocks for Supramolecular Soft-Soft Chain, Helix, and Base-Pair Arrays

  摘要：

  Structure determinations on di-tert-butyliodophosphane selenide 1 and c-hexyldiiodophosphane selenide 2 reveal that intermolecular donor-acceptor interactions between nucleophilic selenium atoms and electrophilic iodine atoms lead to chains or helices that are interconnected by Se Se contacts, building up layer structures. In the adduct of 1 with molecular iodine (3), 1 acts as donor through Se(=P) and as weak acceptor through I(-P). These interactions lead to base-pair-like dimers [tBu(2)P(Se-I-I)I](2) that are interconnected by additional Se ... Se contacts.

  DOI：

  10.1002/(sici)1521-3765(19990104)5:1<385::aid-chem385>3.0.co;2-d
• 作为产物：
  描述：

  环己基溴化镁 在 sodium iodide 、 三氯化磷 作用下， 生成 c-hexyldiiodophosphane
  参考文献：
  名称：

  Iodophosphane Selenides: Building Blocks for Supramolecular Soft-Soft Chain, Helix, and Base-Pair Arrays

  摘要：

  Structure determinations on di-tert-butyliodophosphane selenide 1 and c-hexyldiiodophosphane selenide 2 reveal that intermolecular donor-acceptor interactions between nucleophilic selenium atoms and electrophilic iodine atoms lead to chains or helices that are interconnected by Se Se contacts, building up layer structures. In the adduct of 1 with molecular iodine (3), 1 acts as donor through Se(=P) and as weak acceptor through I(-P). These interactions lead to base-pair-like dimers [tBu(2)P(Se-I-I)I](2) that are interconnected by additional Se ... Se contacts.

  DOI：

  10.1002/(sici)1521-3765(19990104)5:1<385::aid-chem385>3.0.co;2-d