[CdI2(κ1-1,3,5-triaza-7-phosphaadamantane oxide)(μ-1,3,5-triaza-7-phosphaadamantane oxide)] | 1243581-17-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧氮杂膦
• 英文名称: [CdI2(κ1-1,3,5-triaza-7-phosphaadamantane oxide)(μ-1,3,5-triaza-7-phosphaadamantane oxide)]
• CAS: 1243581-17-0
• 化学式: C₁₂H₂₄CdI₂N₆O₂P₂
• 分子量: 712.528
• InChiKey: NBZBICTXLSKXKQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,3,5-triaza-7-phosphaadamantane oxide 、 cadmium(II) iodide 以 甲醇 为溶剂， 以73%的产率得到[CdI2(κ1-1,3,5-triaza-7-phosphaadamantane oxide)(μ-1,3,5-triaza-7-phosphaadamantane oxide)]
  参考文献：
  名称：

  Synthesis, structure, and coordination chemistry of OPTA and SPTA with group 12 metals (PTA=1,3,5-triaza-7-phosphaadamantane)

  摘要：

  Eight group 12 metal complexes of PTA derivatives, [ZnCl2(O=PTA)(H2O)] (1), [ZnCl2(mu-O=PTA)](n) (2), [CdCl2(O=PTA)(H2O)] (3), [Cd(O=PTA)(H2O)Br-2[ (4), [Cdl(2)(kappa(1)-O=PTA)(mu-O=PTA)] (5), [HgCl2(mu-O=PTA)](n) (6), [ZnCl2(S=PTAH)(S=PTAZnCl(3))] (7), and [CdCl2(S=PTA)(CH3OH)](n) (8), have been synthesized, and characterized by IR, elemental analysis, ESI-MS, H-1 and P-31{H-1} NMR, and single-crystal X-ray analysis. Their structures and coordination modes are investigated both in the solid state and in aqueous solution. Their solid-state structures, found to be either dinuclear or polymeric, were elucidated by single-crystal X-ray diffraction. All the metal complexes, however, do not remain intact in aqueous solution as revealed by their H-1 and P-31{H-1} NMR spectroscopic data, and electrospray ionization mass spectrometry. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.05.002