5-(3-Trimethoxysilylpropylamino)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,26,27,28-tetrol | 1269668-65-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 5-(3-Trimethoxysilylpropylamino)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,26,27,28-tetrol
• 英文别名: 5-(3-trimethoxysilylpropylamino)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,26,27,28-tetrol
• CAS: 1269668-65-6
• 化学式: C₃₄H₃₉NO₇Si
• 分子量: 601.772
• InChiKey: MFHAPCZPEHMBIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.87
• 重原子数：
  43
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  121
• 氢给体数：
  5
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  5-amino-25,26,27,28-tetrahydroxycalix[4]arene 、 3-氯丙基三甲氧基硅烷 在 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 生成 5-(3-Trimethoxysilylpropylamino)pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaene-25,26,27,28-tetrol
  参考文献：
  名称：

  Photoactive lanthanide hybrids covalently bonded to functionalized periodic mesoporous organosilica (PMO) by calix[4]arene derivative

  摘要：

  新型发光三元有机-无机介孔杂化材料bpy-Ln-Calix-NH2-PMO (Ln = Eu, Tb; Calix-NH2 = 5-氨基-25,26,27,28-四羟基杯[4]芳烃, PMO =通过共价键组装方法将 Ln3+ 和 2,2'-联吡啶 (bpy) 引入到 Calix-NH2-PMO 杂化材料中组装而成。 FTIR、UV、SAXRD、TEM、N2 吸附测量、光致发光光谱和热重图，结果表明所得材料具有高比表面积、介观结构均匀性和良好的结晶度。此外，与二元介孔杂化物Ln-Calix-NH2-PMO相比，三元介孔杂化物bpy-Ln-Calix-NH2-PMO在发光强度、发光寿命和量子效率方面均表现出整体提高，这表明引入第二配体2,2'-联吡啶可以敏化镧系离子的发光发射。 bpy-Ln-Calix-NH2-PMO 的热重分析表明，由于共价键合到 PMO 基体上，镧系配合物的热稳定性明显提高。

  DOI：

  10.1039/c0jm02526g

文献信息

• Photoactive lanthanide hybrids covalently bonded to functionalized periodic mesoporous organosilica (PMO) by calix[4]arene derivative
  作者：Ya-Juan Li、Li Wang、Bing Yan

  DOI：10.1039/c0jm02526g

  日期：——

  Novel luminescent ternary organic–inorganic mesoprous hybrid materials bpy-Ln-Calix-NH2-PMO (Ln = Eu, Tb; Calix-NH2 = 5-amino-25,26,27,28-tetrahydroxycalix[4]arene, and PMO = periodic mesoporous organosilica) have been assembled by introducing Ln3+ and 2,2′-bipyridine (bpy) into the Calix-NH2-PMO hybrid material through a covalent bond assembling method. FTIR, UV, SAXRD, TEM, N2 adsorption measurements, photoluminescent spectra, and TG plots were obtained, and the results reveal that the resulting materials have high surface area, uniformity in the mesostructure, and good crystallinity. In addition, compared with the binary mesoporous hybrid Ln-Calix-NH2-PMO, the ternary mesoporous hybrids bpy-Ln-Calix-NH2-PMO show an overall increase in luminescent intensity, luminescent lifetime and quantum efficiency, which indicates that the introduction of the second ligand 2,2′-bipyridine can sensitize the luminescence emission of the lanthanide ions. Thermogravimetric analysis on bpy-Ln-Calix-NH2-PMO demonstrated that the thermal stability of the lanthanide complex was evidently improved as it was covalently bonded to the PMO matrix.

  新型发光三元有机-无机介孔杂化材料bpy-Ln-Calix-NH2-PMO (Ln = Eu, Tb; Calix-NH2 = 5-氨基-25,26,27,28-四羟基杯[4]芳烃, PMO =通过共价键组装方法将 Ln3+ 和 2,2'-联吡啶 (bpy) 引入到 Calix-NH2-PMO 杂化材料中组装而成。 FTIR、UV、SAXRD、TEM、N2 吸附测量、光致发光光谱和热重图，结果表明所得材料具有高比表面积、介观结构均匀性和良好的结晶度。此外，与二元介孔杂化物Ln-Calix-NH2-PMO相比，三元介孔杂化物bpy-Ln-Calix-NH2-PMO在发光强度、发光寿命和量子效率方面均表现出整体提高，这表明引入第二配体2,2'-联吡啶可以敏化镧系离子的发光发射。 bpy-Ln-Calix-NH2-PMO 的热重分析表明，由于共价键合到 PMO 基体上，镧系配合物的热稳定性明显提高。
• Calix[4]arene derivative functionalized lanthanide (Eu, Tb) SBA-15 mesoporous hybrids with covalent bonds: assembly, characterization and photoluminescence
  作者：Ya-Juan Li、Bing Yan、Li Wang

  DOI：10.1039/c1dt10190k

  日期：——

  of the resulting lanthanide mesoporous hybrids. The photoluminescent behavior (luminescence, lifetime, quantum efficiency, and energy transfer) for these chemically bonded mesoporous hybrids is studied in detail. Also, their quantum efficiencies are determined, which indicates that the different mesoporous hybrid material systems derived from different functionalized calix[4]arene derivative bridges

  通过共缩合合成三种新型的功能化SBA-15型大孔杯杯[4]芳烃衍生物（Calix-S15，Calix-NO 2 -S15和Calix-NH 2 -S15）。四乙氧基硅烷（TEOS）和改性有机配体（Calix-Si，Calix-NO 2 -Si和Calix-NH 2 -Si）在Pluronic P123表面活性剂作为模板存在的情况下。通过FTIR光谱，29 Si MAS NMR光谱，XRD图谱和N 2吸附-脱附测量证实了这三种母体材料的结构保存。包含共价连接到功能化有序介孔SBA-15上的Ln 3+（Eu 3+，Tb 3+）配合物的三元介孔发光杂种，分别称为Ln（Calix-S15）phen，Ln（Calix-NO 2 -S15 ）phen和Ln（Calix-NH 2-S15）phen是通过共价键组装法将镧系元素离子和1,10-菲咯啉引入相应的母体材料而制得的。利用XRD图谱，TEM和N 2