2-[2-[2-[[2-[2-[2-(4-Methylphenyl)sulfonyloxyethoxy]ethoxy]phenyl]diazenyl]phenoxy]ethoxy]ethyl 4-methylbenzenesulfonate | 223390-04-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 2-[2-[2-[[2-[2-[2-(4-Methylphenyl)sulfonyloxyethoxy]ethoxy]phenyl]diazenyl]phenoxy]ethoxy]ethyl 4-methylbenzenesulfonate
• 英文别名: 2-[2-[2-[[2-[2-[2-(4-methylphenyl)sulfonyloxyethoxy]ethoxy]phenyl]diazenyl]phenoxy]ethoxy]ethyl 4-methylbenzenesulfonate
• CAS: 223390-04-3
• 化学式: C₃₄H₃₈N₂O₁₀S₂
• 分子量: 698.815
• InChiKey: KSNMXMRPTYOXCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  48
• 可旋转键数：
  20
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  165
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  calix<4>arene 、 2-[2-[2-[[2-[2-[2-(4-Methylphenyl)sulfonyloxyethoxy]ethoxy]phenyl]diazenyl]phenoxy]ethoxy]ethyl 4-methylbenzenesulfonate 以19%的产率得到
  参考文献：
  名称：

  A 2,2'-azobenzene-substituted calix[4]arene-crown-6

  摘要：

  The calix[4]arene macrocycle, 25,27-dihydroxy-26,28(O,O' -azobenzene)calix[4]arene-crown-6 [which crystallizes as an N,N-dimethylformamide solvate (C48H46N2O8. C3H7NO)], in the cone conformation, has two opposite phenolic rings bridged by an -(O-CH2-CH2)(2)O-C6H4-N=N-C6H4-(O-CH2-CH2)(2)O-unit. The two other phenolic O atoms are unsubstituted. The azobenzene geometry is the more stable trans one. This structure is compared to other previously reported structures, involving differently bonded azobenzene moieties.

  DOI：

  10.1107/s0108270198013882
• 作为产物：
  描述：

  2,2′-羟基偶氮苯 在 potassium carbonate 、 三乙胺 作用下， 以 二氯甲烷 、 乙腈 为溶剂， 生成 2-[2-[2-[[2-[2-[2-(4-Methylphenyl)sulfonyloxyethoxy]ethoxy]phenyl]diazenyl]phenoxy]ethoxy]ethyl 4-methylbenzenesulfonate
  参考文献：
  名称：

  A 2,2'-azobenzene-substituted calix[4]arene-crown-6

  摘要：

  The calix[4]arene macrocycle, 25,27-dihydroxy-26,28(O,O' -azobenzene)calix[4]arene-crown-6 [which crystallizes as an N,N-dimethylformamide solvate (C48H46N2O8. C3H7NO)], in the cone conformation, has two opposite phenolic rings bridged by an -(O-CH2-CH2)(2)O-C6H4-N=N-C6H4-(O-CH2-CH2)(2)O-unit. The two other phenolic O atoms are unsubstituted. The azobenzene geometry is the more stable trans one. This structure is compared to other previously reported structures, involving differently bonded azobenzene moieties.

  DOI：

  10.1107/s0108270198013882

文献信息

• 一种光敏手性大环分子及其制备方法和用途
  申请人：合肥工业大学

  公开号：CN104496933B

  公开（公告）日：2016-08-17

  本发明公开了一种光敏手性大环分子及其制备方法和用途，属于光响应材料制备领域，该光敏手性大环分子的制备方法，采用下述步骤：a)将寡聚乙二醇，氢氧化钠和对甲基苯磺酰氯在惰性气氛下、四氢呋喃溶剂中反应得到中间体1；b)将所述中间体1、邻二羟基偶氮苯、碳酸铯和二苯并十八冠六溶解在N‑N二甲基甲酰胺溶剂中，在惰性气氛下反应得到中间体2；c)将所述中间体2、手性联萘酚类化合物、碳酸铯和二苯并十八冠六溶解在N‑N二甲基甲酰胺溶剂中，在惰性气氛中反应得到目标产物。本发明的光敏手性大环分子易合成，稳定性好，具有选择性络合手性铵盐的能力，并可通过偶氮顺反异构行为来实现手性铵盐的络合与释放。
• A 2,2'-azobenzene-substituted calix[4]arene-crown-6
  作者：P. Thuéry、M. Nierlich、M. Saadioui、Z. Asfari、J. Vicens

  DOI：10.1107/s0108270198013882

  日期：1999.3.15

  The calix[4]arene macrocycle, 25,27-dihydroxy-26,28(O,O' -azobenzene)calix[4]arene-crown-6 [which crystallizes as an N,N-dimethylformamide solvate (C48H46N2O8. C3H7NO)], in the cone conformation, has two opposite phenolic rings bridged by an -(O-CH2-CH2)(2)O-C6H4-N=N-C6H4-(O-CH2-CH2)(2)O-unit. The two other phenolic O atoms are unsubstituted. The azobenzene geometry is the more stable trans one. This structure is compared to other previously reported structures, involving differently bonded azobenzene moieties.