bis(1,3-aminopropane-κ2N,N')(dicyanamido-κN1)copper(II) perchlorate | 773098-15-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(1,3-aminopropane-κ2N,N')(dicyanamido-κN1)copper(II) perchlorate
• CAS: 773098-15-0
• 化学式: C₈H₂₀CuN₇*ClO₄
• 分子量: 377.29
• InChiKey: KTXPWEOSIWAZQW-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  sodium dicyanamide 、 copper(II) perchlorate 、 1,3-丙二胺 以 水 为溶剂， 生成 bis(1,3-aminopropane-κ2N,N')(dicyanamido-κN1)copper(II) perchlorate
  参考文献：
  名称：

  Low-dimensional compounds containing cyano groups. XII.)copper(II) perchlorate

  摘要：

  The title compound, [Cu(C2N3)(C3H10N2)(2)] ClO4, is made up of [Cu(tn)(2){N(CN)(2)}](+) complex cations (tn is 1,3-diaminopropane) and ClO4- anions. The Cu-II atom is coordinated by four N atoms of two equatorial tn ligands, with an average distance of 2.041 (7) angstrom, and one nitrile N atom of the dicyanamide anion in an axial position, at a distance of 2.236 (3) angstrom, in a manner approaching square-planar coordination geometry. The complex has C-s symmetry, with the mirror plane lying through the central C atoms of both tn ligands and the dca ligand. The ClO4- anion might be considered as very weakly coordinated in the opposite axial position [ Cu - O = 2.705 ( 3) angstrom], thus completing the Cu-II coordination to asymmetric elongated octahedral (4+1+ 1*). The Cu atom and the perchlorate anion both lie on mirror planes.

  DOI：

  10.1107/s0108270105016768