S-(p-tolyl) 2,2-dimethylpentanethioathe | 1258145-44-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚酯
• 英文名称: S-(p-tolyl) 2,2-dimethylpentanethioathe
• CAS: 1258145-44-6
• 化学式: C₁₄H₂₀OS
• 分子量: 236.378
• InChiKey: RUWSPDZFNOESAG-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  对甲苯二硫醚 、 在 hydridotetakis(triphenylphosphine)rhodium(I) 、 三苯基膦 、 1,2-双(二苯基膦)乙烷 作用下， 以 四氢呋喃 为溶剂， 反应 2.0h， 以82%的产率得到S-(p-tolyl) 2,2-dimethylpentanethioathe
  参考文献：
  名称：

  Rhodium-catalyzed interconversion between acid fluorides and thioesters controlled using heteroatom acceptors

  摘要：

  A rhodium complex catalyzed the equilibrium acyl transfer reaction between acid fluorides and thioesters. In the presence of fluoride or thiolate acceptors, the reaction could be shifted to either product. RhH(PPh3)(4)-dppe catalyzed the reaction of acid fluorides and diorgano disulfides in the presence of triphenylphosphine giving thioesters, which was accompanied by triphenylphosphine difluoride. The same complex catalyzed the reaction of aryl thioesters and hexafluorobenzene giving acid fluorides, which was accompanied by 1,4-di(arylthio)-2,3,5,6-tetrafluorobenzenes. (C) 2010 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2010.09.009