bis(trichlorogermyl)ethylene | 5582-70-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(trichlorogermyl)ethylene
• 英文别名: 1,2-Bis(trichlorgermyl)ethylen；1,2-Bis-trichlorgermyl-ethylen；trichloro(2-trichlorogermylethenyl)germane
• CAS: 5582-70-7
• 化学式: C₂H₂Cl₆Ge₂
• 分子量: 383.936
• InChiKey: JRULYNJZBKOHII-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.93
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  锗烷 、 1,2-二氯乙烯 、 四氯化锗 以 neat (no solvent, gas phase) 为溶剂， 以26.2%的产率得到1-Chlor-2-trichlorgermyl-ethylen
  参考文献：
  名称：

  Gas phase reaction of dichlorogermylene with the chlorine-substituted ethylenes

  摘要：

  Gas phase reaction of dichlorogermylenes formed in the systems GeCl4-Si2Cl6 or Ge-GeCl4 with 1,2-dichloroethylene and trichloroethylene was studied. It is shown that:GeCl2 inserts into the C-Cl bond of 1,2-dichloroethylene and forms the derivatives with one or two trichlorogermyl groups. A specific feature of the reaction of:GeCl2 with trichloroethylene was found. In this reaction the formation of only monosubstituted compounds like 1,1-dichloro-2-trichlorogermylethylene and 1,2-dichloro-1-trichlorogermylethylene takes place. The rule established is valid in general also for the reaction of trichloroethylene with dichlorosilylene, another analog of carbene. Reactions taking place in the course of synthesis of organochlorogermanes are considered. DOI: 10.1134/S1070363213020084

  DOI：

  10.1134/s1070363213020084