gold(I)(PtBu3)2Cl | 159161-46-3

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: gold(I)(PtBu3)2Cl
• 英文别名: chlorogold;tritert-butylphosphane
• CAS: 159161-46-3
• 化学式: C₂₄H₅₄AuClP₂
• 分子量: 637.06
• InChiKey: UIAJYKFXTUXGSJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  gold(I)(PtBu3)2Cl 、 sodium trispyrazolylborate 以 二氯甲烷 为溶剂， 以58%的产率得到[Au(hydrotris(pyrazol-1-yl)borate)(P(t)Bu3)]
  参考文献：
  名称：

  Gioia Lobbia, Giancarlo; Hanna, John V.; Pellei, Maura, Dalton Transactions

  摘要：

  DOI：

文献信息

• Chemistry of Polynuclear Cationic Gold(I) Thiolates of Formula [Au ₂ (S <i>t</i> Bu)(L ₂ )][BF ₄ ]
  作者：Pietro Diversi、Angela Cuzzola、Fabio Ghiotto

  DOI：10.1002/ejic.200800918

  日期：2009.2

  AbstractThe reactivity of the gold(I) cationic complexes [Au2(StBu)(L2)][BF4] L = PMe3, PEt3, PtBu3; L2 = dppe [dppe = 1,2‐bis(diphenylphosphanyl)ethane]} was studied. These complexes undergo cleavage of the Au–Au bonds by reaction with phosphanes to give quantitative yields of [Au(StBu)(L)n] and [Au(L)n][BF4] (n = 2 or 3) in the case of monodentate phosphanes, and [Au2(StBu)2(dppe)] and [Au(dppe)2][BF4] in the case of the dppe derivative. These compounds also react with [Au(StBu)(L)] and exchange the neutral moiety bonded to the [Au(L)]+ cation. In both cases some indication of the nature of the intermediates was reached by mass spectrometry (ESI) and NMR spectroscopy. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
• Sladek, Alexander; Schmidbaur, Hubert, Zeitschrift fur Naturforschung, B: Chemical Sciences
  作者：Sladek, Alexander、Schmidbaur, Hubert

  DOI：——

  日期：——