[4-(4-Pentylphenoxy)carbonylphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate | 1426684-84-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: [4-(4-Pentylphenoxy)carbonylphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate
• 英文别名: [4-(4-pentylphenoxy)carbonylphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate
• CAS: 1426684-84-5
• 化学式: C₃₂H₃₄O₇
• 分子量: 530.618
• InChiKey: IRWDUDACUSCFFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  39
• 可旋转键数：
  18
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  88.1
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  4-(4-(丙烯酰氧基)丁氧基)苯甲酸 在 sodium chlorite 、 sodium dihydrogenphosphate dihydrate 、 双氧水 、 甲基磺酰氯 、 4-甲氧基苯酚 、 N,N-二异丙基乙胺 作用下， 以 四氢呋喃 、 水 、 乙腈 为溶剂， 反应 19.0h， 生成 [4-(4-Pentylphenoxy)carbonylphenyl] 4-(4-prop-2-enoyloxybutoxy)benzoate
  参考文献：
  名称：

  POLYMERIZABLE LIQUID CRYSTAL COMPOUND, POLYMERIZABLE COMPOSITION, POLYMER MATERIAL, AND FILM

  摘要：

  公开号：

  EP2754650B1

文献信息

• CHOLESTERIC LIQUID CRYSTAL MIXTURE, FILM, INFRARED REFLECTING PLATE, LAMINATED ARTICLE, AND LAMINATED GLASS
  申请人：Fujifilm Corporation

  公开号：EP2832821A1

  公开（公告）日：2015-02-04

  A cholesteric liquid crystal mixture containing a compound represented by formula (Ia) : Z1-Y1-A1-Y3-M1-Y4-A2-Y2-Z2, a compound represented by formula (Ib) : Z3-Y5-A3-Y7-M2-P, and a tri- or higher functional polymerizable monomer suppresses deposition of a liquid crystal at the time of forming a film, exhibits a wide characteristic reflection bandwidth of a film to be obtained, and suppresses change of a reflection bandwidth caused when laminated glass is manufactured by laminating a liquid crystal film obtained by fixing a cholesteric liquid crystal phase of the film to be obtained with an interlayer film. Z1, Z2 and Z3 represent a polymerizable group; A1, A2 and A3 represent a spacer having an atom-bonding chain length of 1 to 30, provided that the spacer represents an alkylene group, or a linking group of multiple alkylene groups bonding to each other via -O- or -CO-; M1 and M2 represent (-T1-Y8)n-T2-; n indicates a natural number; when n is 2 or more, multiple (-T1-Y8)'s may be the same or different; T1 and T2 represent a saturated or unsaturated hydrocarbon ring, or a saturated or unsaturated heterocyclic ring, provided that the hydrocarbon ring and the heterocyclic ring may have a substituent; Y1, Y2, Y3, Y4, Y5, Y7 and Y8 each independently represent a single bond, -O-, -CO-, -O-CO-, -CO-O- or -O-CO-O-; and P represents a hydrogen atom or an alkyl group having 1 to 15 carbon atoms.

  一种胆甾型液晶混合物，含有由式 (Ia) ：Z1-Y1-A1-Y3-M1-Y4-A2-Y2-Z2、由式 (Ib) ：Z3-Y5-A3-Y7-M2-P，以及一种三官能团或更高官能团的可聚合单体，可抑制成膜时液晶的沉积，使获得的薄膜具有较宽的特性反射带宽，并可抑制通过将获得的薄膜的胆甾液晶相固定而获得的液晶薄膜与中间膜层压而制造层压玻璃时引起的反射带宽变化。Z1、Z2 和 Z3 代表可聚合基团；A1、A2 和 A3 代表原子键合链长度为 1 至 30 的间隔物，条件是间隔物代表亚烷基，或通过 -O- 或 -CO- 相互键合的多个亚烷基的连接基团；M1 和 M2 代表 (-T1-Y8)n-T2-；n 表示自然数；当 n 为 2 或更多时，多个 (-T1-Y8) 可以相同或不同；T1和T2代表饱和或不饱和烃环，或饱和或不饱和杂环，条件是烃环和杂环可以具有取代基；Y1、Y2、Y3、Y4、Y5、Y7和Y8各自独立地代表单键、-O-、-CO-、-O-CO-、-CO-O-或-O-CO-O-；P代表氢原子或具有1至15个碳原子的烷基。
• Optical isomer
  申请人：DIC Corporation

  公开号：US10655066B2

  公开（公告）日：2020-05-19

  The problem that the present invention is to solve is to provide an optical film that has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state. The present invention provides an optical film containing a structural unit derived from a specific compound, that is, an optical film containing a structural unit derived from a compound represented by the general formula (I), which has less alignment defects and is less liable to cause variation in the optical characteristics when placed in a high temperature state, and also provides a display device including the optical film.

  本发明要解决的问题是提供一种光学薄膜，它具有较少的排列缺陷，并且在高温状态下不易引起光学特性的变化。 本发明提供了一种含有由特定化合物衍生的结构单元的光学薄膜，即含有由通式（I）表示的化合物衍生的结构单元的光学薄膜，该光学薄膜具有较少的排列缺陷，并且在高温状态下不易引起光学特性的变化，本发明还提供了一种包括该光学薄膜的显示装置。
• CHOLESTERIC LIQUID CRYSTAL MIXTURE, FILM, SELECTIVE REFLECTIVE PLATE, LAMINATE, LAMINATED GLASS
  申请人：FUJIFILM CORPORATION

  公开号：US20140192286A1

  公开（公告）日：2014-07-10

  A cholesteric liquid-crystal mixture containing a compound represented by the general formula (Ia), a compound represented by the general formula (Ib), a fluorine-containing horizontal alignment agent and a polymerization initiator is capable of forming a film which is prevented from precipitation of liquid-crystal compounds therein, of which the haze is reduced and which has a broad reflection width. Z 1 —Y 1 -A 1 -Y 3 -M 1 -Y 4 -A 2 -Y 2 —Z 2 General Formula (Ia) Z 3 —Y 5 -A 3 -Y 7 -M 2 -P  General Formula (Ib)
• CHOLESTERIC LIQUID CRYSTAL MIXTURE, FILM, IR REFLECTION PLATE, LAMINATE, AND LAMINATED GLASS
  申请人：FUJIFILM Corporation

  公开号：US20150010761A1

  公开（公告）日：2015-01-08

  A cholesteric liquid crystal mixture containing a compound represented by Z 1 -Y 1 -A 1 -Y 3 -M 1 -Y 4 -A 2 -Y 2 -Z 2 , a compound represented by Z 3 -Y 5 -A 3 -Y 7 -M 2 -P, and a tri- or higher functional polymerizable monomer suppresses deposition of a liquid crystal at the time of forming a film, exhibits a wide characteristic reflection bandwidth of the film. Z 1 to Z 3 represent a polymerizable group; A 1 to A 3 represent an alkylene spacer having a chain of 1 to 30 atoms; M 1 and M 2 represent (-T 1 -Y 8 ) n -T 2 -; n indicates a natural number; T 1 and T 2 represent a hydrocarbon or heterocyclic ring; Y 1 to Y 5 , Y 7 and Y 8 represent a single bond, —O—, —CO—, —O—CO—, —CO—O— or —O—CO—O—; and P represents a hydrogen atom or an alkyl group.
• STRESS MEASURING METHOD, STRESS MEASURING MEMBER, AND STRESS MEASURING SET
  申请人：FUJIFILM Corporation

  公开号：US20170030785A1

  公开（公告）日：2017-02-02

  The present invention provides a stress measuring method including: irradiating a photoelastic product including a measurement subject with light penetrating a linear polarizing film and a phase difference film in this order, and detecting reflected light from the product which is derived from the light via the phase difference film and the linear polarizing film in this order, in which in-plane retardation Re (550) of the phase difference film with light having a wavelength of 550 nm satisfies 100 nm≦Re (550 nm)≦700 nm, and in-plane retardation Re (450) of the phase difference film with light having a wavelength of 450 nm satisfies Re (450)/Re (550)≧0.9, a stress measuring member including the linear polarizing film and the phase difference film, and a stress measuring set including the stress measuring member and a stress displaying member including a photoelastic layer.