硫酸锆四水 | 7446-31-3

• 物质功能分类: 无机化工 - 无机盐 - 金属硫化物及硫酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 中文名称: 硫酸锆四水
• 中文别名: 硫酸锆四水合物
• 英文名称: Zirconium sulfate tetrahydrate
• 英文别名: zirconium(4+);disulfate;tetrahydrate
• CAS: 7446-31-3
• 化学式: H8O12S2Zr
• 分子量: 355.4
• InChiKey: NLOQZPHAWQDLQW-UHFFFAOYSA-J

物化性质

• 熔点：
  410 °C
• 密度：
  3.22
• 溶解度：
  极易溶于H2O
• 暴露限值：
  ACGIH: TWA 5 mg/m3; STEL 10 mg/m3NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3
• 稳定性/保质期：
  如果按照规格正确使用和储存，则不会发生分解。该物质易溶于水，并释放大量溶解热，其水溶液呈酸性。在水中，硫酸锆会水解生成二氧化锆水合物（ZrO2·nH2O），形成白色絮状凝胶并具有胶体特性；而不溶于醇。随着溶液浓度的下降和pH值的增高，还会生成碱式硫酸锆。此外，该物质还具有良好的填充性和耐磨性。

计算性质

• 辛醇/水分配系数(LogP)：
  -5.98
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  181
• 氢给体数：
  4
• 氢受体数：
  12

安全信息

• TSCA：
  Yes
• 危险品标志：
  Xi
• 安全说明：
  S26,S37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  28332980
• 危险品运输编号：
  UN 3260 8/PG 3
• WGK Germany：
  3
• RTECS号：
  LV1950000
• 危险类别：
  6.1

SDS

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Section 1: Product Identification
Chemical Name: Zirconium (IV) sulfate tetrahydrate (99.99+%-Zr) PURATREM
CAS Registry Number: 7446-31-3
Formula: Zr(SO4)2.4H2O
EINECS Number: 238-694-4
Chemical Family: metal sulfate
Synonym: Sulfuric acid, zirconium(4+) salt (2:1), Zirconium sulfate

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 7446-31-3 100% 5mg/m3 (as Zr) 5mg/m3 (as Zr)

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Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. This material partially hydrolyzes in water to form dilute sulfuric
Emergency Overview:
acid, a strong irritant.
Primary Routes of Exposure: Ingestion, inhalation, skin, eyes
Eye Contact: Dust is a moderate to severe irritant to the eyes.
Skin Contact: Causes irritation to skin. Symptoms include redness, itching, and pain.
Inhalation: Inhalation of dust may irritate the respiratory tract. Symptoms may include coughing, shortness of breath.
Ingestion: Ingestion may lead to nausea, vomiting and diarrhea.
Acute Health Affects: Acidic behavior causes irritation of skin, eyes and respiratory and gastrointestinal tracts.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: not applicable
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit toxic fumes of sulfur oxides.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up.

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SECTION 7: Handling and Storage
Handling and Storage: Store material in a tightly sealed bottle away from moisture.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear appropriate chemical resistant gloves and protective clothing.
Ventilation: If possible, handle the material in an efficient fume hood.
In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
Respirator:
Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: white xtl.
Molecular Weight: 283.33 (355.39)
Melting Point: 100°C (-3H2O)
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: none
Solubility in Water: soluble

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SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: none
Incompatibility: Strong bases
Decomposition Products: In water, dilute sulfuric acid

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SECTION 11: Toxicological Information
Oral (rat); LD50: 3500 mg/kg. Intraperitoneal (rat); LD50: 175 mg/kg. Subcutaneous (rat); LDLo: 500 mg/kg.
RTECS Data:
Intratesticular (rat); TDLo: 22667 ug/kg. Mouse Lymphocyte; Unscheduled DNA synthesis: 20 umol/L.
Carcinogenic Effects: no data
Mutagenic Effects: no data
Tetratogenic Effects: no data

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: Listed in the TSCA inventory.
SARA (Title 313): Title compound not listed.
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

概述

硫酸锆四水合物又称为四水合硫酸锆，是一种白色结晶性粉末，相对密度为3.22（16℃）。当加热至135～160℃时，它会失去三分子结晶水；而在高于450℃的温度下，则会全部失去结晶水。该物质能溶于水和硫酸，并微溶于乙醇，不溶于碳氢化合物。溶解于水中会产生大量热量，并形成强酸性溶液。通过碱处理或加热，它会发生分解。

用途

硫酸锆四水合物是一种无机化合物，可作为蛋白质的沉淀剂、催化剂和皮革鞣剂，同时也可用作减磨剂和润滑剂等。

反应信息

• 作为反应物：
  描述：

  硫酸锆四水 在 ZrO2 作用下， 以 水 为溶剂， 以Analysis of the solution gave a zirconium content of 195 grams per liter (expressed as ZrO2)的产率得到锆
  参考文献：
  名称：

  Process for the purification of zirconium compounds

  摘要：

  本发明涉及制备锆化合物的方法，经焙烧后形成氧化锆。该锆化合物的制备方法是将氨源添加到水合硫酸锆溶液中，使溶液pH在0.1至2.5范围内，优选在1.0至2.0范围内。从溶液中沉淀出的锆化合物呈结晶状，易于通过过滤收集，并且具有低水平的金属杂质。因此，本发明的方法可用于纯化锆化合物。本发明还包括锆化合物和纯化锆化合物（包括氧化锆）的方法。

  公开号：

  US04822575A1

文献信息

• Process for the purification of zirconium compounds
  申请人：ICI Australia Limited

  公开号：US04822575A1

  公开（公告）日：1989-04-18

  The invention concerns processes for the preparation of zirconium compositions which on calcination form zirconia. The zirconium compositions are prepared by the addition of an ammonia source to an aqueous zirconium sulfate solution to give a solution pH in the range of from 0.1 to 2.5 and preferably 1.0 to 2.0. The zirconium composition precipitated from solution appears crystalline, is readily collected by filtration and has low levels of metallic impurities. Therefore, the process of the invention may be used to advantage in the purification zirconium compounds. The invention also includes the zirconium compositions and processes for the purification of zirconium compounds including zirconia.

  本发明涉及制备锆化合物的方法，经焙烧后形成氧化锆。该锆化合物的制备方法是将氨源添加到水合硫酸锆溶液中，使溶液pH在0.1至2.5范围内，优选在1.0至2.0范围内。从溶液中沉淀出的锆化合物呈结晶状，易于通过过滤收集，并且具有低水平的金属杂质。因此，本发明的方法可用于纯化锆化合物。本发明还包括锆化合物和纯化锆化合物（包括氧化锆）的方法。

表征谱图