[Ni(5-((4-dodecyloxyphenyl)azo)-N-(4-octyloxyphenyl)-salicyladimine-1H)2] | 866572-16-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: [Ni(5-((4-dodecyloxyphenyl)azo)-N-(4-octyloxyphenyl)-salicyladimine-1H)2]
• CAS: 866572-16-9
• 化学式: C₇₈H₁₀₈N₆NiO₆
• 分子量: 1284.44
• InChiKey: LOUKKNBWLYGUEV-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  5-((4-dodecyloxyphenyl)azo)-N-(4-octyloxyphenyl)-salicylaldimine 、 nickel(II) acetate tetrahydrate 以 乙醇 、 氯仿 为溶剂， 以80%的产率得到[Ni(5-((4-dodecyloxyphenyl)azo)-N-(4-octyloxyphenyl)-salicyladimine-1H)2]
  参考文献：
  名称：

  Syntheses, characterization and glass-forming properties of new bis[5-((4-ndodecyloxyphenyl)azo)-N-(4-nalkoxyphenyl)-salicylaldiminato]nickel (II) complex homologues

  摘要：

  A series of bidentate Schiff base ligands, 5-((4-(n)dodecyloxyphenyl)azo)-N-(4-(n)alkoxyphenyl)-salicylaldimine ((n)alkoxy = octyloxy, dodecyloxy, hexadecyloxy) homologues, have been synthesized and characterized by IR, NMR, mass spectroscopy and elemental analyses. Nickel (II) complexes of these ligands were synthesized and characterized by elemental analyses, H-1 NMR and IR spectroscopy. DSC measurements, X-ray powder diffraction experiments and optical polarizing microscopy studies indicated that the Ni complexes have a resistance to crystallization and give an amorphous glassy state but after annealing at room temperature for several days transform to an anisotropic glass. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.03.096