Azanylidyneoxidanium;ruthenium(3+);pentachloride | 86743-54-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Azanylidyneoxidanium;ruthenium(3+);pentachloride
• CAS: 86743-54-6
• 化学式: Cl₅NORu
• 分子量: 308.341
• InChiKey: UBXXTQYDXABYEO-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  -15.09
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Azanylidyneoxidanium;ruthenium(3+);pentachloride 以 乙腈 为溶剂， 生成 cis-[Ru(NO)Cl4(CH3CN)](1-)
  参考文献：
  名称：

  Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}⁶-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2−), and a Characterization of the Product Species

  摘要：

  A one-electron oxidation species of the title complex, [Ru(NO)Cl5]−({RuNO}5-type nitrosyl complex), converted into cis-[Ru(NO)Cl4(CH3CN)]−({RuNO}6-type nitrosyl complex) at low temperature (5 °C) in the dark. The product species could be isolated and characterized. An X-ray structure determination showed a remarkably short N–O bond distance of the Ru–NO moiety: l(N–O) = 0.998 Å, l(Ru–N) = 1.787(5) Å, ∠Ru–N–O = 175.1(6)°. Under room light at 25 °C, the complex underwent a facile nitrosyl photoelimination to give trans-[RuCl4(CH3CN)2]−, the structure of which was also established. During the course of the reactions, two other unidentified species were confirmed to exist by cyclic voltammetry.

  DOI：

  10.1246/bcsj.68.2897
• 作为产物：
  描述：

  tetrabutylammonium pentachloronitrosylruthenate(2-) 以 乙腈 为溶剂， 生成 Azanylidyneoxidanium;ruthenium(3+);pentachloride
  参考文献：
  名称：

  Successive Chemical Reactions Accompanying a One-Electron Oxidation of a {MNO}⁶-Type Nitrosyl Complex, Pentachloro(nitrosyl)ruthenate(2−), and a Characterization of the Product Species

  摘要：

  A one-electron oxidation species of the title complex, [Ru(NO)Cl5]−({RuNO}5-type nitrosyl complex), converted into cis-[Ru(NO)Cl4(CH3CN)]−({RuNO}6-type nitrosyl complex) at low temperature (5 °C) in the dark. The product species could be isolated and characterized. An X-ray structure determination showed a remarkably short N–O bond distance of the Ru–NO moiety: l(N–O) = 0.998 Å, l(Ru–N) = 1.787(5) Å, ∠Ru–N–O = 175.1(6)°. Under room light at 25 °C, the complex underwent a facile nitrosyl photoelimination to give trans-[RuCl4(CH3CN)2]−, the structure of which was also established. During the course of the reactions, two other unidentified species were confirmed to exist by cyclic voltammetry.

  DOI：

  10.1246/bcsj.68.2897

文献信息

• Electrochemical one-electron oxidation of [Ru(NO)Cl₅]^2–: spectroscopic and magnetic evidence for the (t_2g⁵) ruthenium (<scp>III</scp>) pentachloronitrosyl complex monoanion [Ru(NO)Cl₅]^–
  作者：Vyvyan T. Coombe、Graham A. Heath、T. Anthony Stephenson、Derek A. Tocher

  DOI：10.1039/c39830000303

  日期：——

  Voltammetric measurements establish a reversible one-electron oxidation for [Ru(NO)Cl5]2– in CH2Cl2; the i.r. and e.s.r. spectra and magnetic properties of the electrogenerated deep green product are consistent with low- spin [Ru(NO)Cl5]–, and quit different from the properties recently attributed to this anion.