| 104676-59-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 乙烯基酰胺
• CAS: 104676-59-7
• 化学式: C₁₄H₂₂N₄O₄Pt
• 分子量: 505.433
• InChiKey: CWFKUTCHUCUAOO-BFLODASKSA-L

反应信息

• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 cycloheptanedionedioxime 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  High pressure study of changes in energy and intensity of excitations in crystalline metal glyoximes

  摘要：

  The effect of high pressure has been measured on the energy and integrated intensity of electronic excitations of several layered crystals of glyoximes containing Ni, Pd, or Pt. Large changes in both energy and intensity were observed, both of which were completely reversible. The shifts in energy with pressure, are explained in terms of the relative spatial extent of the outer d and p orbitals of Ni, Pd, and Pt. The effects of back donation from the ligands and intensity borrowing from the higher energy charge transfer excitations are considered as possible causes of the observed intensity changes. It was concluded that intensity borrowing was the major cause of the observed changes.

  DOI：

  10.1063/1.451314