copper(I) N-isopropyl-N'-sec-butylacetamidinate | 848737-24-6

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: copper(I) N-isopropyl-N'-sec-butylacetamidinate
• 英文别名: [Cu((i)Pr-Me-(s)Bu-amd)]2
• CAS: 848737-24-6
• 化学式: C₁₈H₃₈Cu₂N₄
• 分子量: 437.619
• InChiKey: QFUIYEXDBXLJPC-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  copper(l) chloride 、 (E)-N′-(sec-butyl)-N-isopropylacetimidamide 在 methyllithium 作用下， 以 乙醚 为溶剂， 以80%的产率得到copper(I) N-isopropyl-N'-sec-butylacetamidinate
  参考文献：
  名称：

  Synthesis and Characterization of Copper(I) Amidinates as Precursors for Atomic Layer Deposition (ALD) of Copper Metal

  摘要：

  A series of copper(I) amidinates of the general type [(R ' NC(R)NR '')Cu](2) (R ' and R '' = n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl; R = methyl, n-butyl) have been synthesized and characterized. These compounds are planar dimers, bridged by nearly linear N-Cu-N bonds. Their properties (volatility, low melting point, high thermal stability, and self-limited surface reactivity) are well-suited for atomic layer deposition (ALD) of copper metal films that are pure, highly conductive, conformal, and strongly adherent to substrates.

  DOI：

  10.1021/ic048492u