| 234079-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• CAS: 234079-09-5
• 化学式: C₁₂H₂₅N₇NiS₃
• 分子量: 422.265
• InChiKey: OHKZNKZWUWUSHP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium 2,4,6-trimercapto-1,3,5-triazinate nonahydrate 、 nickel(II) chloride hexahydrate 、 N,N'-双(3-氨丙基)-1,3-丙二胺 在 0.1 M HCl 作用下， 以 水 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Coordination compounds of nickel with trithiocyanuric acid

  摘要：

  Coordination compounds of compositions [Ni(bapen)(ttcH)] . 2H(2)O (1), [Ni(bappn)(ttcH)] (2), [Ni(mdpta)(ttcH)(H2O)] (3), [Ni(nphen)(2)(ttcH)] . H2O (4), [Ni(nphen)(3)](ttcH). 2H(2)O (5), [Ni(ampy)(2)(ttcH). H2O (6) and [Ni(aepy)(2)(ttcH)]. 2H(2)O (7), where bapen = N,N'-bis(3-aminopropyl)ethylenediamine, bappn = N,N'-bis( 3-aminopropyl)-1,3-propanediamine, mdpta = 3,3'-diamino-N-methyldipropylamine, nphen=5-nitro-1,10-phenanthroline, ampy = 2-aminomethylpyridine, aepy = 2-aminoethylpyridine and ttcH(3) = trithiocyanuric acid, have been prepared. The crystal and molecular structure of (1) was determined by X-ray analysis. Nickel atom is six-coordinated by four N atoms of amine and S and N donor atoms of trithiocyanuric dianion, whereas two water molecules are situated outside the coordination sphere. Cyclic voltammetry showed that the complexes undergo an oxidation attributable to Ni2+-->Ni3+ in the range 550-950 mV. The magnetic behaviour of (6) and (7) has been studied in the 291-94 K temperature range. Magnetic susceptibility follows the Curie-Weiss law. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00053-4