| 493034-01-8

• 分子结构分类: 有机化合物 - 有机磷化合物
• CAS: 493034-01-8
• 化学式: C₁₇H₄₅CuP₄S₂
• 分子量: 501.117
• InChiKey: UPWGWMRWUOPDJC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  7.31
• 重原子数：
  24.0
• 可旋转键数：
  9.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  sodium diisobutyldithiophosphinate 、 copper(l) chloride 、 三甲基膦 以 苯 为溶剂， 以65.6%的产率得到
  参考文献：
  名称：

  Synthesis and X-ray single crystal structures of copper(I) complexes: Cu(S2PiBu2)·(PMe3)3 and Cu(S2PiBu2)·(PPh3)2

  摘要：

  Two new copper(I) complexes Cu((S2PBu2)-Bu-i) . (PMe3)(3) (1) and Cu((S2PBu2)-Bu-i) . (PPh3)(2) (2) have been synthesised and characterised by spectroscopic and X-ray crystallographic methods. Both compounds are monomers in the solid state where copper is four coordinate and the co-ordination geometry is based on a distorted tetrahedron. The dithiophosphinate ligand behaves as a monodentate in compound 1 and bidentate in compound 2. Compound 1 is the only example in Cu(1) complexes with a monodentate dithiophosphinate. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01020-4